Non-hydrothermal synthesis of ID nanostructured manganesebased oxides: Effect of cation substitution on the electrochemical performance of nanowires

Dae Hoon Park, Sun Hee Lee, Tae Woo Kim, Seung Tae Lim, Seong Ju Hwang, Young Soo Yoon, Young Ho Lee, Jin Ho Choy

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Abstract

The synthesis of cation-substituted ID manganese oxide nanowires is achieved via a non-hydrothermal oxidation reaction using a solid-state precursor and conventional glassware. By changing the reaction conditions and precursor composition, it is possible to control the crystal structure and chemical composition of the resulting ID nanostructured materials. The nanowires are found to exhibit promising electrochemical properties as cathode materials in lithium secondary batteries; moreover, the electrochemical properties of the nanowires can be improved by the partial replacement of Mn with Cr3+ cations. The measurements strongly suggest that the cation composition of the nanostructured metal oxides is very important for optimizing their electrode performance. The non-hydrothermal solution synthesis method presented here provides an effective composition-tailored approach for the fabrication of large quantities of ID manganese oxide nanowires.

Original languageEnglish
Pages (from-to)2949-2956
Number of pages8
JournalAdvanced Functional Materials
Volume17
Issue number15
DOIs
Publication statusPublished - 2007 Oct 15

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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