Nonaqueous capillary electrophoretic assays of p-phenylene-bis-4-4'-(1-aryl-2,6-diphenylpyridinium) molecular wires

Martin Pumera, Jindřich Jindřich, Michal Velášek, Jaroslav Pecka

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A nonaqueous CE system for separation and detection of novel electron-dopable molecular wires based on p-phenylene-bis-4,4′-(1-aryl-2,6-diphenylpyridinium) oligomers is described. The method is based on the coupling of CE separation in pure organic solvent, DMF with 50 mM acetic acid, and UV detection at 338 nm. The system offers a rapid measurement in less than 20 min for two priority nanowires and their impurities. Calibration data confirmed linear response for all compounds of interest in the concentration range 0.1-1.0 mg/mL. A highly stable response was observed for repetitive injections (RSD ≤ 2.8%, n = 10).

Original languageEnglish
Pages (from-to)4465-4467
Number of pages3
JournalElectrophoresis
Volume26
Issue number23
DOIs
Publication statusPublished - 2005 Dec

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Biochemistry
  • Clinical Biochemistry

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