Abstract
On the basis of two-photon absorption and time-resolved spectroscopic measurements, as supported by theoretical calculations of quantitative aromaticity, a relationship between the nonlinear optical properties and aromaticity index has been established for a series of four fully conjugated pentapyrrolic expanded porphyrins, namely pentaphyrin (1.1.1.1.1), sapphyrin (1.1.1.1.0), isosmaragdyrin (1.1.1.0.0), and orangarin (1.0.1.0.0), all of which proved amenable to study in dichloromethane.
| Original language | English |
|---|---|
| Pages (from-to) | 6930-6931 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 130 |
| Issue number | 22 |
| DOIs | |
| Publication status | Published - 2008 Jun 4 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
}
Nonlinear optical properties as a guide to aromaticity in congeneric pentapyrrolic expanded porphyrins : Pentaphyrin, sapphyrin, isosmaragdyrin, and orangarin. / Zin, Seok Yoon; Cho, Dong Gyu; Kil, Suk Kim; Sessler, Jonathan L.; Kim, Dongho.
In: Journal of the American Chemical Society, Vol. 130, No. 22, 04.06.2008, p. 6930-6931.Research output: Contribution to journal › Article
TY - JOUR
T1 - Nonlinear optical properties as a guide to aromaticity in congeneric pentapyrrolic expanded porphyrins
T2 - Pentaphyrin, sapphyrin, isosmaragdyrin, and orangarin
AU - Zin, Seok Yoon
AU - Cho, Dong Gyu
AU - Kil, Suk Kim
AU - Sessler, Jonathan L.
AU - Kim, Dongho
PY - 2008/6/4
Y1 - 2008/6/4
N2 - On the basis of two-photon absorption and time-resolved spectroscopic measurements, as supported by theoretical calculations of quantitative aromaticity, a relationship between the nonlinear optical properties and aromaticity index has been established for a series of four fully conjugated pentapyrrolic expanded porphyrins, namely pentaphyrin (1.1.1.1.1), sapphyrin (1.1.1.1.0), isosmaragdyrin (1.1.1.0.0), and orangarin (1.0.1.0.0), all of which proved amenable to study in dichloromethane.
AB - On the basis of two-photon absorption and time-resolved spectroscopic measurements, as supported by theoretical calculations of quantitative aromaticity, a relationship between the nonlinear optical properties and aromaticity index has been established for a series of four fully conjugated pentapyrrolic expanded porphyrins, namely pentaphyrin (1.1.1.1.1), sapphyrin (1.1.1.1.0), isosmaragdyrin (1.1.1.0.0), and orangarin (1.0.1.0.0), all of which proved amenable to study in dichloromethane.
UR - http://www.scopus.com/inward/record.url?scp=44449154890&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=44449154890&partnerID=8YFLogxK
U2 - 10.1021/ja801395y
DO - 10.1021/ja801395y
M3 - Article
VL - 130
SP - 6930
EP - 6931
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 22
ER -