Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework

Bo Keun Park, M. Arzu Miah, Gaehang Lee, Youn Jaung Cho, Kwangyeol Lee, Sangwoo Park, Moon Gun Choi, Joon T. Park

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A mono- to di- and triphosphane transformation occurs on treatment of [Ir4(CO)9(PPh3)3] (1) with C 60 to successively afford 2 and 3. The noninnocent, multifunctional C60 ligand plays a crucial role in transforming three PPh3 ligands into a μ3-PPh2(o-C6H4) P(o-C6H4) PPh(η1-o-C6H 4) triphosphane ligand by a series of ortho-phosphanation and ortho-metalation processes on the Ir4 cluster framework.

Original languageEnglish
Pages (from-to)1712-1714
Number of pages3
JournalAngewandte Chemie - International Edition
Volume43
Issue number13
DOIs
Publication statusPublished - 2004 Mar 19

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of 'Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework'. Together they form a unique fingerprint.

  • Cite this

    Park, B. K., Miah, M. A., Lee, G., Cho, Y. J., Lee, K., Park, S., Choi, M. G., & Park, J. T. (2004). Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework. Angewandte Chemie - International Edition, 43(13), 1712-1714. https://doi.org/10.1002/anie.200353290