Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework

Bo Keun Park, M. Arzu Miah, Gaehang Lee, Youn Jaung Cho, Kwangyeol Lee, Sangwoo Park, Moon-Gun Choi, Joon T. Park

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A mono- to di- and triphosphane transformation occurs on treatment of [Ir4(CO)9(PPh3)3] (1) with C 60 to successively afford 2 and 3. The noninnocent, multifunctional C60 ligand plays a crucial role in transforming three PPh3 ligands into a μ3-PPh2(o-C6H4) P(o-C6H4) PPh(η1-o-C6H 4) triphosphane ligand by a series of ortho-phosphanation and ortho-metalation processes on the Ir4 cluster framework.

Original languageEnglish
Pages (from-to)1712-1714
Number of pages3
JournalAngewandte Chemie - International Edition
Volume43
Issue number13
DOIs
Publication statusPublished - 2004 Mar 19

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Fullerenes
Ligands
Carbon Monoxide
fullerene C60

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Park, B. K., Miah, M. A., Lee, G., Cho, Y. J., Lee, K., Park, S., ... Park, J. T. (2004). Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework. Angewandte Chemie - International Edition, 43(13), 1712-1714. https://doi.org/10.1002/anie.200353290
Park, Bo Keun ; Miah, M. Arzu ; Lee, Gaehang ; Cho, Youn Jaung ; Lee, Kwangyeol ; Park, Sangwoo ; Choi, Moon-Gun ; Park, Joon T. / Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework. In: Angewandte Chemie - International Edition. 2004 ; Vol. 43, No. 13. pp. 1712-1714.
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Park, BK, Miah, MA, Lee, G, Cho, YJ, Lee, K, Park, S, Choi, M-G & Park, JT 2004, 'Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework', Angewandte Chemie - International Edition, vol. 43, no. 13, pp. 1712-1714. https://doi.org/10.1002/anie.200353290

Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework. / Park, Bo Keun; Miah, M. Arzu; Lee, Gaehang; Cho, Youn Jaung; Lee, Kwangyeol; Park, Sangwoo; Choi, Moon-Gun; Park, Joon T.

In: Angewandte Chemie - International Edition, Vol. 43, No. 13, 19.03.2004, p. 1712-1714.

Research output: Contribution to journalArticle

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AU - Lee, Gaehang

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AU - Lee, Kwangyeol

AU - Park, Sangwoo

AU - Choi, Moon-Gun

AU - Park, Joon T.

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