Observation of a re-entrant phase transition in the molecular complex tris(μ2-3,5-diisopropyl-1,2,4-triazolato-κ2 N 1:N 2)trigold(I) under high pressure

Christopher H. Woodall, Jeppe Christensen, Jonathan M. Skelton, Lauren E. Hatcher, Andrew Parlett, Paul R. Raithby, Aron Walsh, Stephen C. Parker, Christine M. Beavers, Simon J. Teat, Mourad Intissar, Christian Reber, David R. Allan

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Abstract

We report a molecular crystal that exhibits four successive phase transitions under hydrostatic pressure, driven by aurophilic interactions, with the ground-state structure re-emerging at high pressure. The effect of pressure on two polytypes of tris(μ2-3,5-diisopropyl-1,2,4-triazolato-κ2 N 1:N 2)trigold(I) (denoted Form-I and Form-II) has been analysed using luminescence spectroscopy, single-crystal X-ray diffraction and first-principles computation. A unique phase behaviour was observed in Form-I, with a complex sequence of phase transitions between 1 and 3.5 GPa. The ambient C2/c mother cell transforms to a P21/n phase above 1 GPa, followed by a P21/a phase above 2 GPa and a large-volume C2/c supercell at 2.70 GPa, with the previously observed P21/n phase then reappearing at higher pressure. The observation of crystallographically identical low- and high-pressure P21/n phases makes this a rare example of a re-entrant phase transformation. The phase behaviour has been characterized using detailed crystallographic theory and modelling, and rationalized in terms of molecular structural distortions. The dramatic changes in conformation are correlated with shifts of the luminescence maxima, from a band maximum at 14040 cm-1 at 2.40 GPa, decreasing steeply to 13550 cm-1 at 3 GPa. A similar study of Form-II displays more conventional crystallographic behaviour, indicating that the complex behaviour observed in Form-I is likely to be a direct consequence of the differences in crystal packing between the two polytypes.

Original languageEnglish
Pages (from-to)367-376
Number of pages10
JournalIUCrJ
Volume3
DOIs
Publication statusPublished - 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry
  • Materials Science(all)
  • Condensed Matter Physics

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    Woodall, C. H., Christensen, J., Skelton, J. M., Hatcher, L. E., Parlett, A., Raithby, P. R., Walsh, A., Parker, S. C., Beavers, C. M., Teat, S. J., Intissar, M., Reber, C., & Allan, D. R. (2016). Observation of a re-entrant phase transition in the molecular complex tris(μ2-3,5-diisopropyl-1,2,4-triazolato-κ2 N 1:N 2)trigold(I) under high pressure. IUCrJ, 3, 367-376. https://doi.org/10.1107/S2052252516013129