Odd-even effects of the polar anchoring strength in nematic liquid crystal on rubbed polyimide Langmuir-Blodgett films with alkyl chain lengths

Dae Shik Seo, Shunsuke Kobayashi, Michinori Nishikawa, Jae Hyung Kim, Yoshikazu Yabe

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The odd-even effect of the alkyl chain length of rubbed polyimide Langmuir-Blodgett (LB) films on the extrapolation length of 5CB has been successfully evaluated by measuring polar anchoring strength. The extrapolation length of 5CB for rubbed PI-LB films with even numbers is small compared with odd numbers for alkyl chain lengths of greater than 7 carbons. The extrapolation length of 5CB on rubbed PI-LB films with odd numbers increases gradually as the temperature increases but tends to diverge near the clearing temperature (Tc=35.3°C). The extrapolation length diverges because of rapidly decreasing surface order near Tc. It is suggested that the polar anchoring strength on rubbed PI-LB films with an even number is strong because of relatively high surface ordering caused by more crystalline surfaces. Finally, it is concluded that the odd-even effects of the polar anchoring strength in NLCs are strongly related to the character of the polymer and observed clearly for long alkyl chain lengths.

Original languageEnglish
Number of pages1
JournalApplied Physics Letters
Publication statusPublished - 1995 Dec 1

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Langmuir-Blodgett films
polyimides
extrapolation
liquid crystals
clearing
temperature
carbon
polymers

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

Cite this

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title = "Odd-even effects of the polar anchoring strength in nematic liquid crystal on rubbed polyimide Langmuir-Blodgett films with alkyl chain lengths",
abstract = "The odd-even effect of the alkyl chain length of rubbed polyimide Langmuir-Blodgett (LB) films on the extrapolation length of 5CB has been successfully evaluated by measuring polar anchoring strength. The extrapolation length of 5CB for rubbed PI-LB films with even numbers is small compared with odd numbers for alkyl chain lengths of greater than 7 carbons. The extrapolation length of 5CB on rubbed PI-LB films with odd numbers increases gradually as the temperature increases but tends to diverge near the clearing temperature (Tc=35.3°C). The extrapolation length diverges because of rapidly decreasing surface order near Tc. It is suggested that the polar anchoring strength on rubbed PI-LB films with an even number is strong because of relatively high surface ordering caused by more crystalline surfaces. Finally, it is concluded that the odd-even effects of the polar anchoring strength in NLCs are strongly related to the character of the polymer and observed clearly for long alkyl chain lengths.",
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Odd-even effects of the polar anchoring strength in nematic liquid crystal on rubbed polyimide Langmuir-Blodgett films with alkyl chain lengths. / Seo, Dae Shik; Kobayashi, Shunsuke; Nishikawa, Michinori; Kim, Jae Hyung; Yabe, Yoshikazu.

In: Applied Physics Letters, 01.12.1995.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Odd-even effects of the polar anchoring strength in nematic liquid crystal on rubbed polyimide Langmuir-Blodgett films with alkyl chain lengths

AU - Seo, Dae Shik

AU - Kobayashi, Shunsuke

AU - Nishikawa, Michinori

AU - Kim, Jae Hyung

AU - Yabe, Yoshikazu

PY - 1995/12/1

Y1 - 1995/12/1

N2 - The odd-even effect of the alkyl chain length of rubbed polyimide Langmuir-Blodgett (LB) films on the extrapolation length of 5CB has been successfully evaluated by measuring polar anchoring strength. The extrapolation length of 5CB for rubbed PI-LB films with even numbers is small compared with odd numbers for alkyl chain lengths of greater than 7 carbons. The extrapolation length of 5CB on rubbed PI-LB films with odd numbers increases gradually as the temperature increases but tends to diverge near the clearing temperature (Tc=35.3°C). The extrapolation length diverges because of rapidly decreasing surface order near Tc. It is suggested that the polar anchoring strength on rubbed PI-LB films with an even number is strong because of relatively high surface ordering caused by more crystalline surfaces. Finally, it is concluded that the odd-even effects of the polar anchoring strength in NLCs are strongly related to the character of the polymer and observed clearly for long alkyl chain lengths.

AB - The odd-even effect of the alkyl chain length of rubbed polyimide Langmuir-Blodgett (LB) films on the extrapolation length of 5CB has been successfully evaluated by measuring polar anchoring strength. The extrapolation length of 5CB for rubbed PI-LB films with even numbers is small compared with odd numbers for alkyl chain lengths of greater than 7 carbons. The extrapolation length of 5CB on rubbed PI-LB films with odd numbers increases gradually as the temperature increases but tends to diverge near the clearing temperature (Tc=35.3°C). The extrapolation length diverges because of rapidly decreasing surface order near Tc. It is suggested that the polar anchoring strength on rubbed PI-LB films with an even number is strong because of relatively high surface ordering caused by more crystalline surfaces. Finally, it is concluded that the odd-even effects of the polar anchoring strength in NLCs are strongly related to the character of the polymer and observed clearly for long alkyl chain lengths.

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