On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives

Derek H.R. Barton, Doook Jang, Joseph Cs Jaszberenyi

Research output: Contribution to journalArticle

70 Citations (Scopus)

Abstract

The room temperature deoxygenation of xanthates and thionocarbonates using (n-Bu) 3Sn-H - Et3B - air has been studied, especially with 119Sn N.M.R. spectroscopy. The original conception of tin radical attack on thiocarbonyl is confirmed.

Original languageEnglish
Pages (from-to)3991-3994
Number of pages4
JournalTetrahedron Letters
Volume31
Issue number28
DOIs
Publication statusPublished - 1990 Jan 1

Fingerprint

Tin
Hydrides
Nuclear magnetic resonance spectroscopy
Magnetic Resonance Spectroscopy
Air
Alcohols
Derivatives
Temperature

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

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On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives. / Barton, Derek H.R.; Jang, Doook; Jaszberenyi, Joseph Cs.

In: Tetrahedron Letters, Vol. 31, No. 28, 01.01.1990, p. 3991-3994.

Research output: Contribution to journalArticle

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