One-dimensional confinement in crystallization of P(VDF-TrFE) thin films with transfer-printed metal electrode

Si Woo Hahm, Donyoung Kim, Dahl-Young Khang

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The crystallization of thin polymer film depends on surface/interface properties, due to the fact that molecular chain motion is affected by the presence of the surface. In this work, we measured the ferroelectric properties, crystallinity, chain conformation and surface morphologies of one-dimensionally confined P(VDF-TrFE) thin films using transfer-printed Au film, annealed at elevated temperatures, from just below melting temperature up to 200 C. Crystallization at low temperature, i.e., below melting temperature, the confinement effect has been found to be negligible. At high temperatures, however, confined crystallization has led to superior ferroelectric properties, compared to samples annealed without confinement. These observations have led to two-or three-layer model for those crystallized thin films with or without confinement, respectively. Further, the transfer-printing of metal as a confining surface has been found to be beneficial, compared to vacuum evaporation, due to deposition-induced damages on organic polymer. This confinement-induced retention of ferroelectricity in P(VDF-TrFE) thin films above its melting temperature can extend processing temperature in organic devices using the ferroelectric polymer, such as non-volatile organic memory devices.

Original languageEnglish
Pages (from-to)175-181
Number of pages7
JournalPolymer
Volume55
Issue number1
DOIs
Publication statusPublished - 2014 Jan 14

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Crystallization
Metals
Ferroelectric materials
Melting point
Thin films
Electrodes
Ferroelectricity
Vacuum evaporation
Temperature
Organic polymers
Polymer films
Surface morphology
Conformations
Printing
Polymers
Data storage equipment
Processing

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics

Cite this

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title = "One-dimensional confinement in crystallization of P(VDF-TrFE) thin films with transfer-printed metal electrode",
abstract = "The crystallization of thin polymer film depends on surface/interface properties, due to the fact that molecular chain motion is affected by the presence of the surface. In this work, we measured the ferroelectric properties, crystallinity, chain conformation and surface morphologies of one-dimensionally confined P(VDF-TrFE) thin films using transfer-printed Au film, annealed at elevated temperatures, from just below melting temperature up to 200 C. Crystallization at low temperature, i.e., below melting temperature, the confinement effect has been found to be negligible. At high temperatures, however, confined crystallization has led to superior ferroelectric properties, compared to samples annealed without confinement. These observations have led to two-or three-layer model for those crystallized thin films with or without confinement, respectively. Further, the transfer-printing of metal as a confining surface has been found to be beneficial, compared to vacuum evaporation, due to deposition-induced damages on organic polymer. This confinement-induced retention of ferroelectricity in P(VDF-TrFE) thin films above its melting temperature can extend processing temperature in organic devices using the ferroelectric polymer, such as non-volatile organic memory devices.",
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One-dimensional confinement in crystallization of P(VDF-TrFE) thin films with transfer-printed metal electrode. / Hahm, Si Woo; Kim, Donyoung; Khang, Dahl-Young.

In: Polymer, Vol. 55, No. 1, 14.01.2014, p. 175-181.

Research output: Contribution to journalArticle

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