Deoxygenation by transition-metal-based catalysts is employed to produce a biofuel from fatty acids. In this study, the citric acid/CoMo ratio of an unsupported CoMo catalyst prepared by a sol-gel method was increased from 1 to 7 to investigate its effect on the physicochemical properties and performance of the catalyst. Deoxygenation was carried out at 300 °C under solvent- and hydrogen-free conditions. The CoMo-3 catalyst (e.g., citric acid/CoMo = 3) showed the highest oleic acid conversion rate, C9-C17hydrocarbon selectivity, oxygen removal rate, and biofuel product quality. This catalyst exhibited the best catalytic performance because it had the highest amount of active species (CoMoO4). Catalyst acidity considerably effected on the catalytic performance. Additionally, the citric acid/CoMo ratio affected the formation of single/mixed Co and Mo oxides.
Bibliographical noteFunding Information:
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2018R1D1A1B07048779). This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2019R1I1A1A01062993).
© The Royal Society of Chemistry 2020.
All Science Journal Classification (ASJC) codes
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Energy Engineering and Power Technology