Onset mechanism of jahn-teller distortion in 4 V LiMn2O 4 and its suppression by LiM0.05Mn1.95O 4(M = Co, Ni) coating

Kyung Yoon Chung, Chang Wan Ryu, Kwang Bum Kim

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

There have been several causes for the capacity fading of LiMn 2O4 reported by many authors, which include Mn dissolution into the electrolyte, and the onset of a Jahn-Teller distortion. One of the main remedies suggested to combat those causes has been doping with other transition-metal ions. However, most of the deterioration reactions take place on the LiMn2O4, surface. In this study, LiMn 2O4 was coated with a doped-spinel oxide to combat the causes of capacity fading in LiMn2O4, which modifies only the surface of the electrodes, and its effect was diagnosed using the bending beam method (BBM). The doped-spinel coated LiMn2O4 showed an excellent cycle performance. From the BBM data, it was confirmed that this excellent performance was largely due to the suppression of the Jahn-Teller distortion, which takes place at the end of the cathodic sweep in the 4 V range. Furthermore, the mechanism for the onset and suppression of Jahn-Teller distortion in 4 V LiMn2O4 is proposed based on the strain variations of the stoichiometric, doped, and doped-spinel coated spinel electrodes.

Original languageEnglish
JournalJournal of the Electrochemical Society
Volume152
Issue number4
DOIs
Publication statusPublished - 2005 May 20

Fingerprint

Jahn-Teller effect
spinel
retarding
coatings
Coatings
combat
fading
causes
Electrodes
Transition metals
Metal ions
electrodes
Deterioration
Dissolution
Electrolytes
deterioration
Doping (additives)
Oxides
metal ions
dissolving

All Science Journal Classification (ASJC) codes

  • Electrochemistry
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

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abstract = "There have been several causes for the capacity fading of LiMn 2O4 reported by many authors, which include Mn dissolution into the electrolyte, and the onset of a Jahn-Teller distortion. One of the main remedies suggested to combat those causes has been doping with other transition-metal ions. However, most of the deterioration reactions take place on the LiMn2O4, surface. In this study, LiMn 2O4 was coated with a doped-spinel oxide to combat the causes of capacity fading in LiMn2O4, which modifies only the surface of the electrodes, and its effect was diagnosed using the bending beam method (BBM). The doped-spinel coated LiMn2O4 showed an excellent cycle performance. From the BBM data, it was confirmed that this excellent performance was largely due to the suppression of the Jahn-Teller distortion, which takes place at the end of the cathodic sweep in the 4 V range. Furthermore, the mechanism for the onset and suppression of Jahn-Teller distortion in 4 V LiMn2O4 is proposed based on the strain variations of the stoichiometric, doped, and doped-spinel coated spinel electrodes.",
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Onset mechanism of jahn-teller distortion in 4 V LiMn2O 4 and its suppression by LiM0.05Mn1.95O 4(M = Co, Ni) coating. / Chung, Kyung Yoon; Ryu, Chang Wan; Kim, Kwang Bum.

In: Journal of the Electrochemical Society, Vol. 152, No. 4, 20.05.2005.

Research output: Contribution to journalArticle

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AU - Kim, Kwang Bum

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N2 - There have been several causes for the capacity fading of LiMn 2O4 reported by many authors, which include Mn dissolution into the electrolyte, and the onset of a Jahn-Teller distortion. One of the main remedies suggested to combat those causes has been doping with other transition-metal ions. However, most of the deterioration reactions take place on the LiMn2O4, surface. In this study, LiMn 2O4 was coated with a doped-spinel oxide to combat the causes of capacity fading in LiMn2O4, which modifies only the surface of the electrodes, and its effect was diagnosed using the bending beam method (BBM). The doped-spinel coated LiMn2O4 showed an excellent cycle performance. From the BBM data, it was confirmed that this excellent performance was largely due to the suppression of the Jahn-Teller distortion, which takes place at the end of the cathodic sweep in the 4 V range. Furthermore, the mechanism for the onset and suppression of Jahn-Teller distortion in 4 V LiMn2O4 is proposed based on the strain variations of the stoichiometric, doped, and doped-spinel coated spinel electrodes.

AB - There have been several causes for the capacity fading of LiMn 2O4 reported by many authors, which include Mn dissolution into the electrolyte, and the onset of a Jahn-Teller distortion. One of the main remedies suggested to combat those causes has been doping with other transition-metal ions. However, most of the deterioration reactions take place on the LiMn2O4, surface. In this study, LiMn 2O4 was coated with a doped-spinel oxide to combat the causes of capacity fading in LiMn2O4, which modifies only the surface of the electrodes, and its effect was diagnosed using the bending beam method (BBM). The doped-spinel coated LiMn2O4 showed an excellent cycle performance. From the BBM data, it was confirmed that this excellent performance was largely due to the suppression of the Jahn-Teller distortion, which takes place at the end of the cathodic sweep in the 4 V range. Furthermore, the mechanism for the onset and suppression of Jahn-Teller distortion in 4 V LiMn2O4 is proposed based on the strain variations of the stoichiometric, doped, and doped-spinel coated spinel electrodes.

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