Optical and encapsulation properties of La(OH)3/poly(urethane acrylate) composites

Jung Hyuk Park; Sung Doo Baek; Min Seong Kim; Jin Il Cho; Soo Young Yoon; Sunghee Kim; Suyeon Lee; Youn Sang Kim; Jae Min Myoung

doi:10.1016/j.matchemphys.2020.123281

Optical and encapsulation properties of La(OH)₃/poly(urethane acrylate) composites

Jung Hyuk Park, Sung Doo Baek, Min Seong Kim, Jin Il Cho, Soo Young Yoon, Sunghee Kim, Suyeon Lee, Youn Sang Kim, Jae Min Myoung

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Two lanthanum hydroxide (LH, La(OH)₃) materials, i.e., La(OH)₃ submicroplates (LHSMPs) and La(OH)₃ nanoparticles (LHNPs), were synthesized hydrothermally, and their optical and encapsulation properties were investigated. The surfaces of the LHSMPs and the LHNPs were modified with a coupling agent: [3-(methacryloyloxy)propyl] trimethoxysilane (MPS). To prepare transparent encapsulation composite materials, both types of surface-modified particles were dispersed in a poly(urethane acrylate) (PUA) adhesive polymer binder. The composite film with surface-modified LHNP-PUA exhibited better optical properties (higher transmittance and lower haze) than that with surface-modified LHSMP-PUA owing to smaller particle size. However, the latter was observed to be more advantageous for preventing the permeation of water molecules owing to the larger particle size.

Original language	English
Article number	123281
Journal	Materials Chemistry and Physics
Volume	252
DOIs	https://doi.org/10.1016/j.matchemphys.2020.123281
Publication status	Published - 2020 Sep 15

Bibliographical note

Funding Information:
This work was supported by the Material and Component Industrial Future Growth Engine Program ( 20006551 , Development of APSALD equipment and TFE material process for flexible OLED encapsulation) funded by the Ministry of Trade, Industry & Energy ( MOTIE , Korea) and the LG Display academic industrial cooperation program.

Publisher Copyright:
© 2020 Elsevier B.V.

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics

Access to Document

10.1016/j.matchemphys.2020.123281

Cite this

@article{c77801fbbc8449358dfb2099fbb984ff,

title = "Optical and encapsulation properties of La(OH)3/poly(urethane acrylate) composites",

abstract = "Two lanthanum hydroxide (LH, La(OH)3) materials, i.e., La(OH)3 submicroplates (LHSMPs) and La(OH)3 nanoparticles (LHNPs), were synthesized hydrothermally, and their optical and encapsulation properties were investigated. The surfaces of the LHSMPs and the LHNPs were modified with a coupling agent: [3-(methacryloyloxy)propyl] trimethoxysilane (MPS). To prepare transparent encapsulation composite materials, both types of surface-modified particles were dispersed in a poly(urethane acrylate) (PUA) adhesive polymer binder. The composite film with surface-modified LHNP-PUA exhibited better optical properties (higher transmittance and lower haze) than that with surface-modified LHSMP-PUA owing to smaller particle size. However, the latter was observed to be more advantageous for preventing the permeation of water molecules owing to the larger particle size.",

author = "Park, {Jung Hyuk} and Baek, {Sung Doo} and Kim, {Min Seong} and Cho, {Jin Il} and Yoon, {Soo Young} and Sunghee Kim and Suyeon Lee and Kim, {Youn Sang} and Myoung, {Jae Min}",

note = "Funding Information: This work was supported by the Material and Component Industrial Future Growth Engine Program ( 20006551 , Development of APSALD equipment and TFE material process for flexible OLED encapsulation) funded by the Ministry of Trade, Industry & Energy ( MOTIE , Korea) and the LG Display academic industrial cooperation program. Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = sep,

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doi = "10.1016/j.matchemphys.2020.123281",

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T1 - Optical and encapsulation properties of La(OH)3/poly(urethane acrylate) composites

AU - Park, Jung Hyuk

AU - Baek, Sung Doo

AU - Kim, Min Seong

AU - Cho, Jin Il

AU - Yoon, Soo Young

AU - Kim, Sunghee

AU - Lee, Suyeon

AU - Kim, Youn Sang

AU - Myoung, Jae Min

N1 - Funding Information: This work was supported by the Material and Component Industrial Future Growth Engine Program ( 20006551 , Development of APSALD equipment and TFE material process for flexible OLED encapsulation) funded by the Ministry of Trade, Industry & Energy ( MOTIE , Korea) and the LG Display academic industrial cooperation program. Publisher Copyright: © 2020 Elsevier B.V.

PY - 2020/9/15

Y1 - 2020/9/15

N2 - Two lanthanum hydroxide (LH, La(OH)3) materials, i.e., La(OH)3 submicroplates (LHSMPs) and La(OH)3 nanoparticles (LHNPs), were synthesized hydrothermally, and their optical and encapsulation properties were investigated. The surfaces of the LHSMPs and the LHNPs were modified with a coupling agent: [3-(methacryloyloxy)propyl] trimethoxysilane (MPS). To prepare transparent encapsulation composite materials, both types of surface-modified particles were dispersed in a poly(urethane acrylate) (PUA) adhesive polymer binder. The composite film with surface-modified LHNP-PUA exhibited better optical properties (higher transmittance and lower haze) than that with surface-modified LHSMP-PUA owing to smaller particle size. However, the latter was observed to be more advantageous for preventing the permeation of water molecules owing to the larger particle size.

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