Ordered Mesoporous C3N5 with a Combined Triazole and Triazine Framework and Its Graphene Hybrids for the Oxygen Reduction Reaction (ORR)

In Young Kim; Sungho Kim; Xiaoyan Jin; Selvarajan Premkumar; Goutam Chandra; Nam Suk Lee; Gurudas P. Mane; Seong Ju Hwang; Siva Umapathy; Ajayan Vinu

doi:10.1002/anie.201811061

Ordered Mesoporous C₃N₅ with a Combined Triazole and Triazine Framework and Its Graphene Hybrids for the Oxygen Reduction Reaction (ORR)

In Young Kim, Sungho Kim, Xiaoyan Jin, Selvarajan Premkumar, Goutam Chandra, Nam Suk Lee, Gurudas P. Mane, Seong Ju Hwang, Siva Umapathy, Ajayan Vinu

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

Mesoporous carbon nitrides (MCN) with C₃N₄ stoichiometry could find applications in fields ranging from catalysis, sensing, and adsorption–separation to biotechnology. The extension of the synthesis of MCN with different nitrogen contents and chemical structures promises access to a wider range of applications. Herein we prepare mesoporous C₃N₅ with a combined triazole and triazine framework via a simple self-assembly of 5-amino-1H-tetrazole (5-ATTZ). We are able to hybridize these nanostructures with graphene by using graphene–mesoporous-silica hybrids as a template to tune the electronic properties. DFT calculations and spectroscopic analyses clearly demonstrate that the C₃N₅ consists of 1 triazole and 2 triazine moieties. The triazole-based mesoporous C₃N₅ and its graphene hybrids are found to be highly active for oxygen reduction reaction (ORR) with a higher diffusion-limiting current density and a decreased overpotential than those of bulk g-C₃N₄.

Original language	English
Pages (from-to)	17135-17140
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	52
DOIs	https://doi.org/10.1002/anie.201811061
Publication status	Published - 2018 Dec 21

Bibliographical note

Funding Information:
This work was supported by the program of the Discovery Early Career Researcher Award (DECRA) of the Australian Research Council (ARC) (grant number DE170101069). NEXAFS measurements were undertaken on the Soft X-ray Beamline at Australian Synchrotron. We acknowledge Mr. Peng Tan (Nanjing University) for his support to draw the schematic model of synthetic procedure.

Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.201811061

Cite this

Kim, I. Y., Kim, S., Jin, X., Premkumar, S., Chandra, G., Lee, N. S., Mane, G. P., Hwang, S. J., Umapathy, S., & Vinu, A. (2018). Ordered Mesoporous C₃N₅ with a Combined Triazole and Triazine Framework and Its Graphene Hybrids for the Oxygen Reduction Reaction (ORR). Angewandte Chemie - International Edition, 57(52), 17135-17140. https://doi.org/10.1002/anie.201811061

Kim, In Young ; Kim, Sungho ; Jin, Xiaoyan ; Premkumar, Selvarajan ; Chandra, Goutam ; Lee, Nam Suk ; Mane, Gurudas P. ; Hwang, Seong Ju ; Umapathy, Siva ; Vinu, Ajayan. / Ordered Mesoporous C₃N₅ with a Combined Triazole and Triazine Framework and Its Graphene Hybrids for the Oxygen Reduction Reaction (ORR). In: Angewandte Chemie - International Edition. 2018 ; Vol. 57, No. 52. pp. 17135-17140.

@article{7d6cae878024416cb3e6a4ccab8946c5,

title = "Ordered Mesoporous C3N5 with a Combined Triazole and Triazine Framework and Its Graphene Hybrids for the Oxygen Reduction Reaction (ORR)",

abstract = "Mesoporous carbon nitrides (MCN) with C3N4 stoichiometry could find applications in fields ranging from catalysis, sensing, and adsorption–separation to biotechnology. The extension of the synthesis of MCN with different nitrogen contents and chemical structures promises access to a wider range of applications. Herein we prepare mesoporous C3N5 with a combined triazole and triazine framework via a simple self-assembly of 5-amino-1H-tetrazole (5-ATTZ). We are able to hybridize these nanostructures with graphene by using graphene–mesoporous-silica hybrids as a template to tune the electronic properties. DFT calculations and spectroscopic analyses clearly demonstrate that the C3N5 consists of 1 triazole and 2 triazine moieties. The triazole-based mesoporous C3N5 and its graphene hybrids are found to be highly active for oxygen reduction reaction (ORR) with a higher diffusion-limiting current density and a decreased overpotential than those of bulk g-C3N4.",

author = "Kim, {In Young} and Sungho Kim and Xiaoyan Jin and Selvarajan Premkumar and Goutam Chandra and Lee, {Nam Suk} and Mane, {Gurudas P.} and Hwang, {Seong Ju} and Siva Umapathy and Ajayan Vinu",

note = "Funding Information: This work was supported by the program of the Discovery Early Career Researcher Award (DECRA) of the Australian Research Council (ARC) (grant number DE170101069). NEXAFS measurements were undertaken on the Soft X-ray Beamline at Australian Synchrotron. We acknowledge Mr. Peng Tan (Nanjing University) for his support to draw the schematic model of synthetic procedure. Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2018",

month = dec,

day = "21",

doi = "10.1002/anie.201811061",

language = "English",

volume = "57",

pages = "17135--17140",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "52",

}

Ordered Mesoporous C₃N₅ with a Combined Triazole and Triazine Framework and Its Graphene Hybrids for the Oxygen Reduction Reaction (ORR). / Kim, In Young; Kim, Sungho; Jin, Xiaoyan; Premkumar, Selvarajan; Chandra, Goutam; Lee, Nam Suk; Mane, Gurudas P.; Hwang, Seong Ju; Umapathy, Siva; Vinu, Ajayan.

In: Angewandte Chemie - International Edition, Vol. 57, No. 52, 21.12.2018, p. 17135-17140.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Ordered Mesoporous C3N5 with a Combined Triazole and Triazine Framework and Its Graphene Hybrids for the Oxygen Reduction Reaction (ORR)

AU - Kim, In Young

AU - Kim, Sungho

AU - Jin, Xiaoyan

AU - Premkumar, Selvarajan

AU - Chandra, Goutam

AU - Lee, Nam Suk

AU - Mane, Gurudas P.

AU - Hwang, Seong Ju

AU - Umapathy, Siva

AU - Vinu, Ajayan

N1 - Funding Information: This work was supported by the program of the Discovery Early Career Researcher Award (DECRA) of the Australian Research Council (ARC) (grant number DE170101069). NEXAFS measurements were undertaken on the Soft X-ray Beamline at Australian Synchrotron. We acknowledge Mr. Peng Tan (Nanjing University) for his support to draw the schematic model of synthetic procedure. Publisher Copyright: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2018/12/21

Y1 - 2018/12/21

N2 - Mesoporous carbon nitrides (MCN) with C3N4 stoichiometry could find applications in fields ranging from catalysis, sensing, and adsorption–separation to biotechnology. The extension of the synthesis of MCN with different nitrogen contents and chemical structures promises access to a wider range of applications. Herein we prepare mesoporous C3N5 with a combined triazole and triazine framework via a simple self-assembly of 5-amino-1H-tetrazole (5-ATTZ). We are able to hybridize these nanostructures with graphene by using graphene–mesoporous-silica hybrids as a template to tune the electronic properties. DFT calculations and spectroscopic analyses clearly demonstrate that the C3N5 consists of 1 triazole and 2 triazine moieties. The triazole-based mesoporous C3N5 and its graphene hybrids are found to be highly active for oxygen reduction reaction (ORR) with a higher diffusion-limiting current density and a decreased overpotential than those of bulk g-C3N4.

AB - Mesoporous carbon nitrides (MCN) with C3N4 stoichiometry could find applications in fields ranging from catalysis, sensing, and adsorption–separation to biotechnology. The extension of the synthesis of MCN with different nitrogen contents and chemical structures promises access to a wider range of applications. Herein we prepare mesoporous C3N5 with a combined triazole and triazine framework via a simple self-assembly of 5-amino-1H-tetrazole (5-ATTZ). We are able to hybridize these nanostructures with graphene by using graphene–mesoporous-silica hybrids as a template to tune the electronic properties. DFT calculations and spectroscopic analyses clearly demonstrate that the C3N5 consists of 1 triazole and 2 triazine moieties. The triazole-based mesoporous C3N5 and its graphene hybrids are found to be highly active for oxygen reduction reaction (ORR) with a higher diffusion-limiting current density and a decreased overpotential than those of bulk g-C3N4.

UR - http://www.scopus.com/inward/record.url?scp=85057470806&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85057470806&partnerID=8YFLogxK

U2 - 10.1002/anie.201811061

DO - 10.1002/anie.201811061

M3 - Article

C2 - 30407712

AN - SCOPUS:85057470806

VL - 57

SP - 17135

EP - 17140

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 52

ER -