Abstract
Chemical modification of polybutadiene was achieved by orthoalkylation of aromatic ketimine with the vinyl group of polybutadiene using a rhodium(I) catalyst. A high 2-acylphenyl group-impregnation ratio was observed with low vinyl group polybutadiene, likely due to decreased steric congestion between the pendant orthoalkylated groups in the modified polybutadiene.
| Original language | English |
|---|---|
| Pages (from-to) | 1059-1062 |
| Number of pages | 4 |
| Journal | Synlett |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2007 Apr 24 |
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All Science Journal Classification (ASJC) codes
- Organic Chemistry
Cite this
Jo, E. A., Cho, E. G., & Jun, C. H. (2007). Orthoalkylation of aromatic ketimine with the vinyl group in polybutadiene using a rhodium(I) catalyst. Synlett, (7), 1059-1062. https://doi.org/10.1055/s-2007-977426