Orthoalkylation of aromatic ketimine with the vinyl group in polybutadiene using a rhodium(I) catalyst

Eun Ae Jo, Eung Goo Cho, Chul Ho Jun

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

Chemical modification of polybutadiene was achieved by orthoalkylation of aromatic ketimine with the vinyl group of polybutadiene using a rhodium(I) catalyst. A high 2-acylphenyl group-impregnation ratio was observed with low vinyl group polybutadiene, likely due to decreased steric congestion between the pendant orthoalkylated groups in the modified polybutadiene.

Original languageEnglish
Pages (from-to)1059-1062
Number of pages4
JournalSynlett
Issue number7
DOIs
Publication statusPublished - 2007 Apr 24

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Rhodium
Catalysts
Chemical modification
Impregnation
polybutadiene
ketimine

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Jo, Eun Ae ; Cho, Eung Goo ; Jun, Chul Ho. / Orthoalkylation of aromatic ketimine with the vinyl group in polybutadiene using a rhodium(I) catalyst. In: Synlett. 2007 ; No. 7. pp. 1059-1062.
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Jo, EA, Cho, EG & Jun, CH 2007, 'Orthoalkylation of aromatic ketimine with the vinyl group in polybutadiene using a rhodium(I) catalyst', Synlett, no. 7, pp. 1059-1062. https://doi.org/10.1055/s-2007-977426

Orthoalkylation of aromatic ketimine with the vinyl group in polybutadiene using a rhodium(I) catalyst. / Jo, Eun Ae; Cho, Eung Goo; Jun, Chul Ho.

In: Synlett, No. 7, 24.04.2007, p. 1059-1062.

Research output: Contribution to journal › Article

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Jo EA, Cho EG, Jun CH. Orthoalkylation of aromatic ketimine with the vinyl group in polybutadiene using a rhodium(I) catalyst. Synlett. 2007 Apr 24;(7):1059-1062. https://doi.org/10.1055/s-2007-977426

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