Oxidation behavior of hot-pressed Si3N4 with Re2O3 (Re=Y, Yb, Er, La)

Heon Jin Choi, June Gunn Lee, Young Wook Kim

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Four different β-Si3N4 ceramics with silicon oxynitrides [Y10(SiO4)6N2, Yb4Si2N2O7, Er2Si3N4O3, and La10(SiO4)6N2, respectively] as secondary phases have been fabricated by hot-pressing the Si3N4-Re4Si2N2O 7 (Re=Y, Yb, Er, and La) compositions at 1820°C for 2 h under a pressure of 25 MPa. The oxidation behavior of the hot-pressed ceramics was characterized and compared with that of the ceramics fabricated from Si3N4-Re2Si2O7 compositions. All Si3N4 ceramics investigated herein showed a parabolic weight gain with oxidation time at 1400°C and the oxidation products of the ceramics were SiO2 and Re2Si2O7. The Si3N4-Re4Si2N2O 7 compositions showed inferior oxidation resistance to those from Si3N4-Re2Si2O7 compositions, owing to the incompatibility of the secondary phases of those ceramics with SiO2, the oxidation product of Si3N4. Si3N4 ceramics from a Si3N4-Er4Si2N2O 7 composition showed the best oxidation resistance of 0·198 mg cm-2 after oxidation at 1400°C for 192 h in air among the compositions investigated herein.

Original languageEnglish
Pages (from-to)2757-2762
Number of pages6
JournalJournal of the European Ceramic Society
Volume19
Issue number16
Publication statusPublished - 1999 Dec 1

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Oxidation
Chemical analysis
Oxidation resistance
Hot pressing
silicon nitride
Silicon
Air

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Choi, Heon Jin ; Lee, June Gunn ; Kim, Young Wook. / Oxidation behavior of hot-pressed Si3N4 with Re2O3 (Re=Y, Yb, Er, La). In: Journal of the European Ceramic Society. 1999 ; Vol. 19, No. 16. pp. 2757-2762.
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Oxidation behavior of hot-pressed Si3N4 with Re2O3 (Re=Y, Yb, Er, La). / Choi, Heon Jin; Lee, June Gunn; Kim, Young Wook.

In: Journal of the European Ceramic Society, Vol. 19, No. 16, 01.12.1999, p. 2757-2762.

Research output: Contribution to journalArticle

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AU - Choi, Heon Jin

AU - Lee, June Gunn

AU - Kim, Young Wook

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