Oxocyclohexadienylidene-substituted subporphyrins

Shin Ya Hayashi, Jooyoung Sung, Young Mo Sung, Yasuhide Inokuma, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Quinonoidal subporphyrin analogue 2 was synthesized by oxidation of meso-tris(3,5-di-tert-butyl-4-hydroxyphenyl)subporphyrin 1 (see scheme). Compound 2 was readily deprotonated to generate anionic species 3. These three macrocycles were structurally characterized, including the full delocalization of the anionic charge in 3.

Original languageEnglish
Pages (from-to)3253-3256
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number14
DOIs
Publication statusPublished - 2011 Mar 28

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Oxidation
3,5-di-tert-butyl-4-hydroxyphenyl

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis

Cite this

Hayashi, S. Y., Sung, J., Sung, Y. M., Inokuma, Y., Kim, D., & Osuka, A. (2011). Oxocyclohexadienylidene-substituted subporphyrins. Angewandte Chemie - International Edition, 50(14), 3253-3256. https://doi.org/10.1002/anie.201006449
Hayashi, Shin Ya ; Sung, Jooyoung ; Sung, Young Mo ; Inokuma, Yasuhide ; Kim, Dongho ; Osuka, Atsuhiro. / Oxocyclohexadienylidene-substituted subporphyrins. In: Angewandte Chemie - International Edition. 2011 ; Vol. 50, No. 14. pp. 3253-3256.
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Hayashi, SY, Sung, J, Sung, YM, Inokuma, Y, Kim, D & Osuka, A 2011, 'Oxocyclohexadienylidene-substituted subporphyrins', Angewandte Chemie - International Edition, vol. 50, no. 14, pp. 3253-3256. https://doi.org/10.1002/anie.201006449

Oxocyclohexadienylidene-substituted subporphyrins. / Hayashi, Shin Ya; Sung, Jooyoung; Sung, Young Mo; Inokuma, Yasuhide; Kim, Dongho; Osuka, Atsuhiro.

In: Angewandte Chemie - International Edition, Vol. 50, No. 14, 28.03.2011, p. 3253-3256.

Research output: Contribution to journalArticle

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