Oxocyclohexadienylidene-substituted subporphyrins

Shin Ya Hayashi, Jooyoung Sung, Young Mo Sung, Yasuhide Inokuma, Dongho Kim, Atsuhiro Osuka

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12 Citations (Scopus)

Abstract

Quinonoidal subporphyrin analogue 2 was synthesized by oxidation of meso-tris(3,5-di-tert-butyl-4-hydroxyphenyl)subporphyrin 1 (see scheme). Compound 2 was readily deprotonated to generate anionic species 3. These three macrocycles were structurally characterized, including the full delocalization of the anionic charge in 3.

Original languageEnglish
Pages (from-to)3253-3256
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number14
DOIs
Publication statusPublished - 2011 Mar 28

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Hayashi, S. Y., Sung, J., Sung, Y. M., Inokuma, Y., Kim, D., & Osuka, A. (2011). Oxocyclohexadienylidene-substituted subporphyrins. Angewandte Chemie - International Edition, 50(14), 3253-3256. https://doi.org/10.1002/anie.201006449