Palladium-Catalyzed Carbonylative Esterification of Primary Alcohols with Aryl Chlorides through Dehydroxymethylative C-C Bond Cleavage

Hyo Soon Park, Dong Su Kim, Chul Ho Jun

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Aryl chlorides in the presence of Pd/C catalyst and NaF react with primary alcohols to form esters, arenes, and alkanes. In this reaction, aryl chlorides act as both oxidants and coupling partners, whereas alcohols serve as both carbonyl sources and alkoxy components of the ester products. (Formula Presented).

Original languageEnglish
Pages (from-to)397-401
Number of pages5
JournalACS Catalysis
Volume5
Issue number1
DOIs
Publication statusPublished - 2015 Jan 2

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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