Palladium-Catalyzed Carbonylative Esterification of Primary Alcohols with Aryl Chlorides through Dehydroxymethylative C-C Bond Cleavage

Hyo Soon Park, Dong Su Kim, Chul-Ho Jun

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Aryl chlorides in the presence of Pd/C catalyst and NaF react with primary alcohols to form esters, arenes, and alkanes. In this reaction, aryl chlorides act as both oxidants and coupling partners, whereas alcohols serve as both carbonyl sources and alkoxy components of the ester products. (Formula Presented).

Original languageEnglish
Pages (from-to)397-401
Number of pages5
JournalACS Catalysis
Volume5
Issue number1
DOIs
Publication statusPublished - 2015 Jan 2

Fingerprint

Esterification
Palladium
Chlorides
Esters
Alcohols
Alkanes
Oxidants
Paraffins
Catalysts
alkoxyl radical

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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Palladium-Catalyzed Carbonylative Esterification of Primary Alcohols with Aryl Chlorides through Dehydroxymethylative C-C Bond Cleavage. / Park, Hyo Soon; Kim, Dong Su; Jun, Chul-Ho.

In: ACS Catalysis, Vol. 5, No. 1, 02.01.2015, p. 397-401.

Research output: Contribution to journalArticle

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