Two Pd-Cu alloy membrane modules were designed to recover high-purity hydrogen from a mixture at elevated temperature and pressure. Permeation and separation behavior were studied experimentally and theoretically using pure hydrogen gas and a binary mixture of H 2 /CO 2 (58.2: 41.8 in vol%) at 250–350 °C and 800–1,200 kPa. The Pd-Cu membrane modules presented a maximum permeation flux at the highest temperature (350 °C) and pressure (1,200 kPa) both for pure H 2 gas and the binary mixture. When the permeate and retentate flowed in the same direction in the membrane module (co-current flow), a temperature gradient and permeation flux variations were observed and the permeance of the H 2 /CO 2 mixture was 2.263×10 −4 mL/(cm 2 ·s·Pa 0.5 ) at 250 °C and 3.409×10 −4 mL/(cm 2 ·s·Pa 0.5 ) at 350 °C. On the other hand, when the retentate flowed in the opposite direction to the permeate flow (counter-current flow), the temperature gradient and permeation flux variations were significantly reduced and the permeation flux improved by about 11% from that of the co-current flow module. The well-distributed temperature profile inside the module and increased hydrogen pressure difference through the membrane layer shortened the time to reach the steady state in the counter-current Pd-Cu membrane module, thus enhancing the membrane performance. The results of this study can contribute towards developing an efficient Pd-Cu membrane reactor.
Bibliographical noteFunding Information:
This research was supported by the National Strategic Project-Carbon Reuse of the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT; Ministry of Environment; and Ministry of Trade, Industry, and Energy. (2017M3D8A2084029).
All Science Journal Classification (ASJC) codes
- Chemical Engineering(all)