Partially Fluorinated Multiblock Poly(arylene ether sulfone) Membranes for Fuel Cell Applications

Sojeong Lee, Jinok Yuk, Adam F. Nugraha, Yong-Gun Shul, Seok Hee Park, Dongwon Shin, Byungchan Bae

Research output: Contribution to journalArticle

Abstract

Sulfonated poly(arylene ether sulfone) (SPAES-F series) membranes, which are partially fluorinated multiblock polymers containing Bisphenol 6F (6F-BPA), are synthesized. The membranes exhibit less water uptake and higher ion conductivity at similar ion exchange capacity (IEC) values compared to previous SPAES membranes containing identical hydrophilic blocks. This is attributed to the presence of 6F-BPA in the hydrophobic block, which enhances hydrophobicity and promotes phase separation, as observed through transmission electron microscopy analysis. F4 (IEC = 2.4 meq g−1) shows superior ion conductivity than Nafion NRE212 membrane irrespective of the humidity level. Furthermore, the SPAES electrolyte membrane of 1.5 meq g−1 produces better performance than NRE212, yielding a current density of 488 mA cm−2 at 80 °C, 80% RH, and 0.6 V. In 50% RH at 80 °C, SPAES with 1.5 meq g−1 exhibits a cell resistance and fuel cell performance comparable to those of NRE212; clearly, regulating hydrophobicity and hydrophilicity is crucial for enhanced performance.

Original languageEnglish
Article number1700650
JournalMacromolecular Materials and Engineering
Volume303
Issue number5
DOIs
Publication statusPublished - 2018 May 1

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Sulfones
Ether
Fuel cells
Ethers
Membranes
Hydrophobicity
Ion exchange
Ions
Hydrophilicity
Phase separation
Electrolytes
Atmospheric humidity
Polymers
Current density
Transmission electron microscopy
Water

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Lee, Sojeong ; Yuk, Jinok ; Nugraha, Adam F. ; Shul, Yong-Gun ; Park, Seok Hee ; Shin, Dongwon ; Bae, Byungchan. / Partially Fluorinated Multiblock Poly(arylene ether sulfone) Membranes for Fuel Cell Applications. In: Macromolecular Materials and Engineering. 2018 ; Vol. 303, No. 5.
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abstract = "Sulfonated poly(arylene ether sulfone) (SPAES-F series) membranes, which are partially fluorinated multiblock polymers containing Bisphenol 6F (6F-BPA), are synthesized. The membranes exhibit less water uptake and higher ion conductivity at similar ion exchange capacity (IEC) values compared to previous SPAES membranes containing identical hydrophilic blocks. This is attributed to the presence of 6F-BPA in the hydrophobic block, which enhances hydrophobicity and promotes phase separation, as observed through transmission electron microscopy analysis. F4 (IEC = 2.4 meq g−1) shows superior ion conductivity than Nafion NRE212 membrane irrespective of the humidity level. Furthermore, the SPAES electrolyte membrane of 1.5 meq g−1 produces better performance than NRE212, yielding a current density of 488 mA cm−2 at 80 °C, 80{\%} RH, and 0.6 V. In 50{\%} RH at 80 °C, SPAES with 1.5 meq g−1 exhibits a cell resistance and fuel cell performance comparable to those of NRE212; clearly, regulating hydrophobicity and hydrophilicity is crucial for enhanced performance.",
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Partially Fluorinated Multiblock Poly(arylene ether sulfone) Membranes for Fuel Cell Applications. / Lee, Sojeong; Yuk, Jinok; Nugraha, Adam F.; Shul, Yong-Gun; Park, Seok Hee; Shin, Dongwon; Bae, Byungchan.

In: Macromolecular Materials and Engineering, Vol. 303, No. 5, 1700650, 01.05.2018.

Research output: Contribution to journalArticle

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