Pd/C-Catalyzed Carbonylative Esterification of Aryl Halides with Alcohols by Using Oxiranes as CO Sources

Byul Hana Min, Dong Su Kim, Hyo Soon Park, Chul-Ho Jun

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

A carbonylative esterification reaction between aryl bromides and alcohols, promoted by Pd/C and NaF in the presence of oxiranes, has been developed. In this process, oxiranes serve as sources of carbon monoxide by their conversion to aldehydes through a palladium-promoted Meinwald rearrangement pathway. Intramolecular versions of this process serve as methods for the synthesis of lactones and phthalimides. CO gas free! A carbonylative esterification reaction between aryl bromides and alcohols, promoted by Pd/C and NaF in the presence of oxiranes, has been developed. In this process, oxiranes serve as sources of carbon monoxide by their conversion to aldehydes through a palladium-promoted Meinwald rearrangement pathway (see scheme).

Original languageEnglish
Pages (from-to)6234-6238
Number of pages5
JournalChemistry - A European Journal
Volume22
Issue number18
DOIs
Publication statusPublished - 2016 Apr 25

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Epoxy Compounds
Esterification
Carbon Monoxide
Aldehydes
Carbon monoxide
Palladium
Alcohols
Bromides
Phthalimides
Lactones
Gases

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

Cite this

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title = "Pd/C-Catalyzed Carbonylative Esterification of Aryl Halides with Alcohols by Using Oxiranes as CO Sources",
abstract = "A carbonylative esterification reaction between aryl bromides and alcohols, promoted by Pd/C and NaF in the presence of oxiranes, has been developed. In this process, oxiranes serve as sources of carbon monoxide by their conversion to aldehydes through a palladium-promoted Meinwald rearrangement pathway. Intramolecular versions of this process serve as methods for the synthesis of lactones and phthalimides. CO gas free! A carbonylative esterification reaction between aryl bromides and alcohols, promoted by Pd/C and NaF in the presence of oxiranes, has been developed. In this process, oxiranes serve as sources of carbon monoxide by their conversion to aldehydes through a palladium-promoted Meinwald rearrangement pathway (see scheme).",
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Pd/C-Catalyzed Carbonylative Esterification of Aryl Halides with Alcohols by Using Oxiranes as CO Sources. / Min, Byul Hana; Kim, Dong Su; Park, Hyo Soon; Jun, Chul-Ho.

In: Chemistry - A European Journal, Vol. 22, No. 18, 25.04.2016, p. 6234-6238.

Research output: Contribution to journalArticle

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