PdII complexes of [44]-and [46]decaphyrins: The largest hückel aromatic and antiaromatic, and Möbius aromatic macrocycles

Tomoki Yoneda, Young Mo Sung, Jong Min Lim, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Reductive metalation of [44]decaphyrin with [Pd2-(dba)3] provided a Hückel aromatic [46]decaphyrin PdII complex, which was readily oxidized upon treatment with DDQ to produce a Hückel antiaromatic [44]decaphyrin PdII complex. In CH2Cl2 solution the latter complex underwent slow tautomerization to a Möbius aromatic [44]decaphyrin PdII complex which exists as a mixture of conformers in dynamic equilibrium. To the best of our knowledge, these three PdII complexes represent the largest Hückel aromatic, Hückel antiaromatic, and Möbius aromatic complexes to date.

Original languageEnglish
Pages (from-to)13169-13173
Number of pages5
JournalAngewandte Chemie - International Edition
Volume53
Issue number48
DOIs
Publication statusPublished - 2014 Nov 24

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

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title = "PdII complexes of [44]-and [46]decaphyrins: The largest h{\"u}ckel aromatic and antiaromatic, and M{\"o}bius aromatic macrocycles",
abstract = "Reductive metalation of [44]decaphyrin with [Pd2-(dba)3] provided a H{\"u}ckel aromatic [46]decaphyrin PdII complex, which was readily oxidized upon treatment with DDQ to produce a H{\"u}ckel antiaromatic [44]decaphyrin PdII complex. In CH2Cl2 solution the latter complex underwent slow tautomerization to a M{\"o}bius aromatic [44]decaphyrin PdII complex which exists as a mixture of conformers in dynamic equilibrium. To the best of our knowledge, these three PdII complexes represent the largest H{\"u}ckel aromatic, H{\"u}ckel antiaromatic, and M{\"o}bius aromatic complexes to date.",
author = "Tomoki Yoneda and Sung, {Young Mo} and Lim, {Jong Min} and Dongho Kim and Atsuhiro Osuka",
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PdII complexes of [44]-and [46]decaphyrins : The largest hückel aromatic and antiaromatic, and Möbius aromatic macrocycles. / Yoneda, Tomoki; Sung, Young Mo; Lim, Jong Min; Kim, Dongho; Osuka, Atsuhiro.

In: Angewandte Chemie - International Edition, Vol. 53, No. 48, 24.11.2014, p. 13169-13173.

Research output: Contribution to journalArticle

TY - JOUR

T1 - PdII complexes of [44]-and [46]decaphyrins

T2 - The largest hückel aromatic and antiaromatic, and Möbius aromatic macrocycles

AU - Yoneda, Tomoki

AU - Sung, Young Mo

AU - Lim, Jong Min

AU - Kim, Dongho

AU - Osuka, Atsuhiro

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AB - Reductive metalation of [44]decaphyrin with [Pd2-(dba)3] provided a Hückel aromatic [46]decaphyrin PdII complex, which was readily oxidized upon treatment with DDQ to produce a Hückel antiaromatic [44]decaphyrin PdII complex. In CH2Cl2 solution the latter complex underwent slow tautomerization to a Möbius aromatic [44]decaphyrin PdII complex which exists as a mixture of conformers in dynamic equilibrium. To the best of our knowledge, these three PdII complexes represent the largest Hückel aromatic, Hückel antiaromatic, and Möbius aromatic complexes to date.

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