Performance characterization and kinetic modeling of ozonation using a new method: ROH,O3 concept

Minhwan Kwon, Homin Kye, Youmi Jung, Yeojoon Yoon, Joonwun Kang

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Ozonation is an effective treatment for removing various organic pollutants from aquatic systems. The Rct concept, which is defined as the ratio of [rad]OH exposure to O3 exposure, has been widely used to predict the removal efficiency of target compounds, but it has significant variations by water temperature and initial O3 dose which are crucial parameters in drinking water plant. The ROH,O3 concept, which is defined as the [rad]OH exposure by O3 consumption, was proposed as a kinetic parameter for characterization and kinetic modeling for ozonation. The ROH,O3 concept is independent of temperature and initial O3 dose. A higher ROH,O3 value indicates a higher [rad]OH formation when the same amount of O3 is consumed in different water samples; therefore, the [rad]OH yield from O3 decomposition of the water samples can be compared using the ROH,O3 values. The ROH,O3 concept can also be used to characterize and model the initial ozone demand phase, and it is more convenient method compared to Rct concept. Using the ROH,O3 concept, the dynamic O3 and [rad]OH kinetics and the removal efficiencies of iopromide and ibuprofen were well predicted (R2 = 0.98) over a wide range of experimental conditions (n = 124).

Original languageEnglish
Pages (from-to)172-182
Number of pages11
JournalWater Research
Volume122
DOIs
Publication statusPublished - 2017 Jan 1

Fingerprint

Ozonization
kinetics
Kinetics
modeling
Water
Organic pollutants
Kinetic parameters
organic pollutant
Potable water
Ozone
water temperature
drinking water
ozone
decomposition
Decomposition
water
Temperature
method
exposure
ozonation

All Science Journal Classification (ASJC) codes

  • Ecological Modelling
  • Water Science and Technology
  • Waste Management and Disposal
  • Pollution

Cite this

Kwon, Minhwan ; Kye, Homin ; Jung, Youmi ; Yoon, Yeojoon ; Kang, Joonwun. / Performance characterization and kinetic modeling of ozonation using a new method : ROH,O3 concept. In: Water Research. 2017 ; Vol. 122. pp. 172-182.
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Performance characterization and kinetic modeling of ozonation using a new method : ROH,O3 concept. / Kwon, Minhwan; Kye, Homin; Jung, Youmi; Yoon, Yeojoon; Kang, Joonwun.

In: Water Research, Vol. 122, 01.01.2017, p. 172-182.

Research output: Contribution to journalArticle

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