Pet/bio-based terpolyester blends with high dimensional thermal stability

Sangyoon Park, Sarinthip Thanakkasaranee, Hojun Shin, Youngsoo Lee, Guman Tak, Jongchul Seo

Research output: Contribution to journalArticlepeer-review

Abstract

To improve the dimensional thermal stability of polyethylene terephthalate (PET), a poly(ethylene glycol 1,4-cyclohexane dimethylene (CHDM) isosorbide (ISB) terephthalate) (PEICT) known as ECOZEN® T110 (EZT) was introduced into PET using a melt blending technique. The mis-cibility, morphology, and thermal properties of the PET/EZT samples were investigated. The introduction of amorphous EZT into semi-crystalline PET increased the glass transition temperature (Tg) but decreased the crystallinity, which could be related to the transesterification reaction. By adding EZT contents up to 20%, the PET/EZT samples showed a single Tg, which indicated the miscibility between PET and EZT. However, two Tg values were observed in the PET/EZT samples with higher EZT contents (30–70%), indicating partial miscibility. This may have been due to the slightly different rheological and thermodynamic parameters that were affected by a higher ratio of bulky (rigid ISB and ductile CHDM) groups in EZT. However, the heat distortion temperature of the PET/EZT samples remarkably increased, which indicated that the dimensional stability was truly enhanced. Although the crystallinity of the PET/EZT samples decreased with increasing EZT content, the tensile strength and Young’s modulus decreased slightly. Based on these results, the as-prepared PET/EZT samples with high dimensional stability can be used as a high-temperature polymeric material in various applications.

Original languageEnglish
Article number728
Pages (from-to)1-13
Number of pages13
JournalPolymers
Volume13
Issue number5
DOIs
Publication statusPublished - 2021 Mar 1

Bibliographical note

Publisher Copyright:
© 2021 by the authors. Licensee MDPI, Basel, Switzerland.

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Polymers and Plastics

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