Phase behavior of a weakly interacting polystyrene and poly(n-hexyl methacrylate) system: Evidence for the coexistence of UCST and LCST

Hyungju Ahn, Sudhakar Naidu, Du Yeol Ryu, Junhan Cho

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The phase behavior of a weakly interacting binary system composed of deuterated polystyrene (dPS) and poly(n-hexyl methacrylate) (PnHMA) was investigated by the turbidity measurement for the binary blend, and by small angle X-ray scattering (SAXS) and depolarized light scattering for the block copolymers. For the binary dPS/PnHMA blend, a new phase diagram involving both the upper critical solution transition (UCST) and lower critical solution transition (LCST) was observed by the delicate control of molecular weights between dPS and PnHMA. Whereas for the block copolymers such as dPS-block-PnHMA and PS-block-PnHMA, an order-to-disorder transition (ODT) on heating was observed within the experimental temperature range depending on the molecular weight. This coexistence of both a UCST and LCST in the dPS/PnHMA blend consequently represents the experimental evidence that the corresponding (d)PS-b-PnHMAs possess not only ODT, but also lower disorder-to-order transition (LDOT) character driven by a compressibility difference, although the latter is hindered by thermal degradation.

Original languageEnglish
Pages (from-to)469-474
Number of pages6
JournalMacromolecular Rapid Communications
Volume30
Issue number6
DOIs
Publication statusPublished - 2009 Mar 19

Fingerprint

Polystyrenes
Phase behavior
Block copolymers
Molecular weight
Turbidity
X ray scattering
Compressibility
Light scattering
Phase diagrams
Pyrolysis
hexyl methacrylate
Heating
Temperature

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

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abstract = "The phase behavior of a weakly interacting binary system composed of deuterated polystyrene (dPS) and poly(n-hexyl methacrylate) (PnHMA) was investigated by the turbidity measurement for the binary blend, and by small angle X-ray scattering (SAXS) and depolarized light scattering for the block copolymers. For the binary dPS/PnHMA blend, a new phase diagram involving both the upper critical solution transition (UCST) and lower critical solution transition (LCST) was observed by the delicate control of molecular weights between dPS and PnHMA. Whereas for the block copolymers such as dPS-block-PnHMA and PS-block-PnHMA, an order-to-disorder transition (ODT) on heating was observed within the experimental temperature range depending on the molecular weight. This coexistence of both a UCST and LCST in the dPS/PnHMA blend consequently represents the experimental evidence that the corresponding (d)PS-b-PnHMAs possess not only ODT, but also lower disorder-to-order transition (LDOT) character driven by a compressibility difference, although the latter is hindered by thermal degradation.",
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Phase behavior of a weakly interacting polystyrene and poly(n-hexyl methacrylate) system : Evidence for the coexistence of UCST and LCST. / Ahn, Hyungju; Naidu, Sudhakar; Ryu, Du Yeol; Cho, Junhan.

In: Macromolecular Rapid Communications, Vol. 30, No. 6, 19.03.2009, p. 469-474.

Research output: Contribution to journalArticle

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