Phase Behavior of Polystyrene-block-poly(n-butyl methacrylate) Copolymers with Various End-Functional Groups

Unyong Jeong, Du Yeol Ryu, Jin Kon Kim

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The effect of end-functional group on the phase behavior of block copolymers was analyzed. The effect was studied using small-angle x-ray scattering, transmission electron microscopy (TEM), polarized optical microscopy (POM) and rheology. The molecular weight of polystyrene precursor was measured by size exclusion chromatography. The results show that the addition of only one end-functional group to polystyrene-block-poly(n-butyl methacrylate) changed the lower disordered-to-ordered transition (LDOT).

Original languageEnglish
Pages (from-to)8913-8918
Number of pages6
JournalMacromolecules
Volume36
Issue number24
DOIs
Publication statusPublished - 2003 Dec 2

Fingerprint

Polystyrenes
Phase behavior
Functional groups
Copolymers
Size exclusion chromatography
Rheology
Block copolymers
Optical microscopy
Molecular weight
Scattering
Transmission electron microscopy
X rays
poly(butyl methacrylate)

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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Phase Behavior of Polystyrene-block-poly(n-butyl methacrylate) Copolymers with Various End-Functional Groups. / Jeong, Unyong; Ryu, Du Yeol; Kim, Jin Kon.

In: Macromolecules, Vol. 36, No. 24, 02.12.2003, p. 8913-8918.

Research output: Contribution to journalArticle

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