Photoacoustic effect on the electrical and mechanical properties of polymer-infiltrated carbon nanotube fiber/graphene oxide composites

Ki Ho Nam, Yong O. Im, Hye Jin Park, Haena Lee, Junbeom Park, Sunho Jeong, Seung Min Kim, Nam Ho You, Jae Hak Choi, Haksoo Han, Kun Hong Lee, Bon Cheol Ku

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Direct spinning of carbon nanotube (CNT) fibers is a facile method to produce CNT fibers because of its high productivity and the simplicity of the spinning process from CNT aerogels. Directly spun CNT fibers, however, generally include amorphous carbon and weak shear interaction between tubes or bundles, thereby causing insufficient load transfer. Here, we report newly designed polyimide/reduced graphene oxide (PI/RGO)/CNT fiber composites in combination with polymer infiltration followed by photonic flash sintering on a time scale of 0.5 ms to overcome the critical drawbacks in directly spun CNT fibers. The mechanical performances of the CNT fibers were closely related to the junction strength in CNT bundles. In addition, PI can be interlocked with CNT bundles and effectively serve as a binder to link the GO and CNT fibers with strong interfacial interactions. The PI infiltrated CNT fibers showed the highest load transfer, resulting in a significantly enhanced increase of 83% in specific strength (1.1 N/tex) and a 477% increase in tensile strength (800 MPa) compared to pristine CNT fibers. Furthermore, the photonic sintered PI/RGO/CNT fibers improved electrical conductivity by over 244% (5.5 × 103 S cm−1) over pristine CNT fibers without deteriorating mechanical properties. The results demonstrate that the mechanical strength, modulus and electrical conductivity can be enhanced simultaneously by molecular-level coupling of polymer/graphene with CNT fibers via photonic flash sintering.

Original languageEnglish
Pages (from-to)136-144
Number of pages9
JournalComposites Science and Technology
Volume153
DOIs
Publication statusPublished - 2017 Dec 1

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Carbon Nanotubes
Graphite
Photoacoustic effect
Oxides
Graphene
Carbon nanotubes
Polymers
Electric properties
Mechanical properties
Fibers
Composite materials
Photonics
Polyimides
Sintering
Spinning (fibers)
Aerogels
Amorphous carbon
Infiltration

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Engineering(all)

Cite this

Nam, Ki Ho ; Im, Yong O. ; Park, Hye Jin ; Lee, Haena ; Park, Junbeom ; Jeong, Sunho ; Kim, Seung Min ; You, Nam Ho ; Choi, Jae Hak ; Han, Haksoo ; Lee, Kun Hong ; Ku, Bon Cheol. / Photoacoustic effect on the electrical and mechanical properties of polymer-infiltrated carbon nanotube fiber/graphene oxide composites. In: Composites Science and Technology. 2017 ; Vol. 153. pp. 136-144.
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abstract = "Direct spinning of carbon nanotube (CNT) fibers is a facile method to produce CNT fibers because of its high productivity and the simplicity of the spinning process from CNT aerogels. Directly spun CNT fibers, however, generally include amorphous carbon and weak shear interaction between tubes or bundles, thereby causing insufficient load transfer. Here, we report newly designed polyimide/reduced graphene oxide (PI/RGO)/CNT fiber composites in combination with polymer infiltration followed by photonic flash sintering on a time scale of 0.5 ms to overcome the critical drawbacks in directly spun CNT fibers. The mechanical performances of the CNT fibers were closely related to the junction strength in CNT bundles. In addition, PI can be interlocked with CNT bundles and effectively serve as a binder to link the GO and CNT fibers with strong interfacial interactions. The PI infiltrated CNT fibers showed the highest load transfer, resulting in a significantly enhanced increase of 83{\%} in specific strength (1.1 N/tex) and a 477{\%} increase in tensile strength (800 MPa) compared to pristine CNT fibers. Furthermore, the photonic sintered PI/RGO/CNT fibers improved electrical conductivity by over 244{\%} (5.5 × 103 S cm−1) over pristine CNT fibers without deteriorating mechanical properties. The results demonstrate that the mechanical strength, modulus and electrical conductivity can be enhanced simultaneously by molecular-level coupling of polymer/graphene with CNT fibers via photonic flash sintering.",
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Photoacoustic effect on the electrical and mechanical properties of polymer-infiltrated carbon nanotube fiber/graphene oxide composites. / Nam, Ki Ho; Im, Yong O.; Park, Hye Jin; Lee, Haena; Park, Junbeom; Jeong, Sunho; Kim, Seung Min; You, Nam Ho; Choi, Jae Hak; Han, Haksoo; Lee, Kun Hong; Ku, Bon Cheol.

In: Composites Science and Technology, Vol. 153, 01.12.2017, p. 136-144.

Research output: Contribution to journalArticle

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T1 - Photoacoustic effect on the electrical and mechanical properties of polymer-infiltrated carbon nanotube fiber/graphene oxide composites

AU - Nam, Ki Ho

AU - Im, Yong O.

AU - Park, Hye Jin

AU - Lee, Haena

AU - Park, Junbeom

AU - Jeong, Sunho

AU - Kim, Seung Min

AU - You, Nam Ho

AU - Choi, Jae Hak

AU - Han, Haksoo

AU - Lee, Kun Hong

AU - Ku, Bon Cheol

PY - 2017/12/1

Y1 - 2017/12/1

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