Photocurrent generation of poly(titanyloxo-phthalocyanine)s and silica hybrid film

Duk Sang Han, Ying Jun Lee, Jeong Soo Kim, Eunkyoung Kim

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Photoelectric properties of poly(titanyloxo-phthalocyanine) bound silica hybrid film were investigated. The solution for the silica hybrid film consists of soluble poly(titanyloxo-phthalocyanine) (PTiOPc) and a sol solution prepared from the hydrolysis of r-glycidoxypropyl-trimethoxysilane and methyl trimethoxysilane. PTiOPc-silica hybrid films were prepared from the above solution by sol-gel process, to give transparent film. The film showed pencil hardness of 3-H when coated on a glass substrate. The PTiOPc-silica hybrid films coated on an ITO glass showed photocurrent higher than 4 μA/cm2, upon excitation with a visible light under an external potential of 0.6 V (versus Ag/AgCl). The photoconductivity was not much affected by the bridging group between the phthalocyanine ring, but linearly dependent on the content of PTiOPc up to 40 wt.%.

Original languageEnglish
Pages (from-to)203-205
Number of pages3
JournalSynthetic Metals
Volume117
Issue number1-3
DOIs
Publication statusPublished - 2001 Feb 15

Fingerprint

Photocurrents
Silicon Dioxide
photocurrents
Silica
silicon dioxide
ITO glass
glass
Photoconductivity
Polymethyl Methacrylate
sol-gel processes
Sols
ITO (semiconductors)
photoconductivity
Sol-gel process
hydrolysis
phthalocyanine
Hydrolysis
hardness
Hardness
Glass

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Han, Duk Sang ; Lee, Ying Jun ; Kim, Jeong Soo ; Kim, Eunkyoung. / Photocurrent generation of poly(titanyloxo-phthalocyanine)s and silica hybrid film. In: Synthetic Metals. 2001 ; Vol. 117, No. 1-3. pp. 203-205.
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Photocurrent generation of poly(titanyloxo-phthalocyanine)s and silica hybrid film. / Han, Duk Sang; Lee, Ying Jun; Kim, Jeong Soo; Kim, Eunkyoung.

In: Synthetic Metals, Vol. 117, No. 1-3, 15.02.2001, p. 203-205.

Research output: Contribution to journalArticle

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