Photoresponsive palladium(II) complexes with azobenzene incorporated into benzyl aryl ether dendrimers

Sangwoo Park; Oleg N. Kadkin; Ji Geon Tae; Moon Gun Choi

doi:10.1016/j.ica.2008.02.023

Photoresponsive palladium(II) complexes with azobenzene incorporated into benzyl aryl ether dendrimers

Sangwoo Park, Oleg N. Kadkin, Ji Geon Tae, Moon Gun Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Palladium(II) complexes, [Pd(GX-azb)₂Cl₂] (where azb = azobenzene, GX = benzyl-aryl ether dendron of generation X = 1, 2, 3), were prepared and their photophysical properties were examined. The synthesized complexes were characterized by chemical analysis, ¹H NMR and UV spectroscopy. The photochromic dendritic azobenzene ligands within the complexes [Pd(GX-azb)₂Cl₂] undergo a reversible trans/cis isomerization upon exposure to ultraviolet light.

Original language	English
Pages (from-to)	3063-3068
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	361
Issue number	11
DOIs	https://doi.org/10.1016/j.ica.2008.02.023
Publication status	Published - 2008 Jul 27

Bibliographical note

Funding Information:
This work was supported by a grant from the Korea Science and Engineering Foundation through Center for Bioactive Molecular Hybrids (CBMH), and Yonsei University Research Grant.

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2008.02.023

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title = "Photoresponsive palladium(II) complexes with azobenzene incorporated into benzyl aryl ether dendrimers",

abstract = "Palladium(II) complexes, [Pd(GX-azb)2Cl2] (where azb = azobenzene, GX = benzyl-aryl ether dendron of generation X = 1, 2, 3), were prepared and their photophysical properties were examined. The synthesized complexes were characterized by chemical analysis, 1H NMR and UV spectroscopy. The photochromic dendritic azobenzene ligands within the complexes [Pd(GX-azb)2Cl2] undergo a reversible trans/cis isomerization upon exposure to ultraviolet light.",

author = "Sangwoo Park and Kadkin, {Oleg N.} and Tae, {Ji Geon} and Choi, {Moon Gun}",

note = "Funding Information: This work was supported by a grant from the Korea Science and Engineering Foundation through Center for Bioactive Molecular Hybrids (CBMH), and Yonsei University Research Grant.",

year = "2008",

month = jul,

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doi = "10.1016/j.ica.2008.02.023",

language = "English",

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pages = "3063--3068",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Photoresponsive palladium(II) complexes with azobenzene incorporated into benzyl aryl ether dendrimers

AU - Park, Sangwoo

AU - Kadkin, Oleg N.

AU - Tae, Ji Geon

AU - Choi, Moon Gun

N1 - Funding Information: This work was supported by a grant from the Korea Science and Engineering Foundation through Center for Bioactive Molecular Hybrids (CBMH), and Yonsei University Research Grant.

PY - 2008/7/27

Y1 - 2008/7/27

N2 - Palladium(II) complexes, [Pd(GX-azb)2Cl2] (where azb = azobenzene, GX = benzyl-aryl ether dendron of generation X = 1, 2, 3), were prepared and their photophysical properties were examined. The synthesized complexes were characterized by chemical analysis, 1H NMR and UV spectroscopy. The photochromic dendritic azobenzene ligands within the complexes [Pd(GX-azb)2Cl2] undergo a reversible trans/cis isomerization upon exposure to ultraviolet light.

AB - Palladium(II) complexes, [Pd(GX-azb)2Cl2] (where azb = azobenzene, GX = benzyl-aryl ether dendron of generation X = 1, 2, 3), were prepared and their photophysical properties were examined. The synthesized complexes were characterized by chemical analysis, 1H NMR and UV spectroscopy. The photochromic dendritic azobenzene ligands within the complexes [Pd(GX-azb)2Cl2] undergo a reversible trans/cis isomerization upon exposure to ultraviolet light.

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DO - 10.1016/j.ica.2008.02.023

M3 - Article

AN - SCOPUS:46849122236

SN - 0020-1693

VL - 361

SP - 3063

EP - 3068

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 11

ER -

Photoresponsive palladium(II) complexes with azobenzene incorporated into benzyl aryl ether dendrimers

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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