Physicochemical characteristics of ZnS immobilized on spherical activated carbon for removing HA(humic acid)

Joon Jae Lee, Jeong Kwon Suh, Ji Sook Hong, Jung Min Lee, Jin Won Park

Research output: Chapter in Book/Report/Conference proceedingConference contribution

4 Citations (Scopus)

Abstract

In this study, spherical activated carbons contained ZnS(Zn-SPAC) were successfully prepared through carbonization/activation processes. Strong acid ion exchange resin as starting material of Zn-SPAC was treated by 0.01 N zinc solution. Ion exchange treatment was performed from one time to three times for controling zinc content. The ion exchanged resins was activated under N 2/H2O-vapor atmosphere at 900°C for 0.5 hr following by carbonization treatment at 700°C under N2 atmosphere. The Zn-SPAC samples were measured physicochemical characteristics such as X-ray patterns, SEM image, energy dispersive X-ray spectra, BET specific surface area, intensity and zinc content and used to remove humic acid(HA) in batch reactor for measuring photochemical activity. The X-ray patterns were appeared ZnS type. The Zn-SPAC had large BET specific surface area and their shape was spherical with a diameter about 350 - 400 μm. When the Zn-SPAC were dosed in UV reactor, the HA removal efficiency increased upto 60 % at 4hr. The order hand, the HA removal efficiency by only UV-C(λmax = 254nm) irradiation was not good about 15 %. Therefore, we infer that the Zn-SPAC have good photochemical activity and presented possibility of photocatalyst for water purification.

Original languageEnglish
Title of host publicationEco-Materials Processing and Design IX - Selected, peer reviewed papers from 9th International Symposium on Eco-Materials Processing and Design
PublisherTrans Tech Publications Ltd
Pages37-40
Number of pages4
ISBN (Print)9770255547605
DOIs
Publication statusPublished - 2008 Jan 1
Event9th International Symposium on Eco-Materials Processing and Design - Changwon City, Korea, Republic of
Duration: 2008 Jan 72008 Jan 9

Publication series

NameMaterials Science Forum
Volume569
ISSN (Print)0255-5476

Other

Other9th International Symposium on Eco-Materials Processing and Design
CountryKorea, Republic of
CityChangwon City
Period08/1/708/1/9

Fingerprint

Humic Substances
activated carbon
Activated carbon
Zinc
Carbonization
Specific surface area
X rays
acids
carbonization
zinc
Ion Exchange Resins
Ion exchange resins
reactors
Batch reactors
Photocatalysts
ion exchange resins
atmospheres
x rays
Purification
water treatment

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Lee, J. J., Suh, J. K., Hong, J. S., Lee, J. M., & Park, J. W. (2008). Physicochemical characteristics of ZnS immobilized on spherical activated carbon for removing HA(humic acid). In Eco-Materials Processing and Design IX - Selected, peer reviewed papers from 9th International Symposium on Eco-Materials Processing and Design (pp. 37-40). (Materials Science Forum; Vol. 569). Trans Tech Publications Ltd. https://doi.org/10.4028/0-87849-472-3.37
Lee, Joon Jae ; Suh, Jeong Kwon ; Hong, Ji Sook ; Lee, Jung Min ; Park, Jin Won. / Physicochemical characteristics of ZnS immobilized on spherical activated carbon for removing HA(humic acid). Eco-Materials Processing and Design IX - Selected, peer reviewed papers from 9th International Symposium on Eco-Materials Processing and Design. Trans Tech Publications Ltd, 2008. pp. 37-40 (Materials Science Forum).
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title = "Physicochemical characteristics of ZnS immobilized on spherical activated carbon for removing HA(humic acid)",
abstract = "In this study, spherical activated carbons contained ZnS(Zn-SPAC) were successfully prepared through carbonization/activation processes. Strong acid ion exchange resin as starting material of Zn-SPAC was treated by 0.01 N zinc solution. Ion exchange treatment was performed from one time to three times for controling zinc content. The ion exchanged resins was activated under N 2/H2O-vapor atmosphere at 900°C for 0.5 hr following by carbonization treatment at 700°C under N2 atmosphere. The Zn-SPAC samples were measured physicochemical characteristics such as X-ray patterns, SEM image, energy dispersive X-ray spectra, BET specific surface area, intensity and zinc content and used to remove humic acid(HA) in batch reactor for measuring photochemical activity. The X-ray patterns were appeared ZnS type. The Zn-SPAC had large BET specific surface area and their shape was spherical with a diameter about 350 - 400 μm. When the Zn-SPAC were dosed in UV reactor, the HA removal efficiency increased upto 60 {\%} at 4hr. The order hand, the HA removal efficiency by only UV-C(λmax = 254nm) irradiation was not good about 15 {\%}. Therefore, we infer that the Zn-SPAC have good photochemical activity and presented possibility of photocatalyst for water purification.",
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Lee, JJ, Suh, JK, Hong, JS, Lee, JM & Park, JW 2008, Physicochemical characteristics of ZnS immobilized on spherical activated carbon for removing HA(humic acid). in Eco-Materials Processing and Design IX - Selected, peer reviewed papers from 9th International Symposium on Eco-Materials Processing and Design. Materials Science Forum, vol. 569, Trans Tech Publications Ltd, pp. 37-40, 9th International Symposium on Eco-Materials Processing and Design, Changwon City, Korea, Republic of, 08/1/7. https://doi.org/10.4028/0-87849-472-3.37

Physicochemical characteristics of ZnS immobilized on spherical activated carbon for removing HA(humic acid). / Lee, Joon Jae; Suh, Jeong Kwon; Hong, Ji Sook; Lee, Jung Min; Park, Jin Won.

Eco-Materials Processing and Design IX - Selected, peer reviewed papers from 9th International Symposium on Eco-Materials Processing and Design. Trans Tech Publications Ltd, 2008. p. 37-40 (Materials Science Forum; Vol. 569).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - In this study, spherical activated carbons contained ZnS(Zn-SPAC) were successfully prepared through carbonization/activation processes. Strong acid ion exchange resin as starting material of Zn-SPAC was treated by 0.01 N zinc solution. Ion exchange treatment was performed from one time to three times for controling zinc content. The ion exchanged resins was activated under N 2/H2O-vapor atmosphere at 900°C for 0.5 hr following by carbonization treatment at 700°C under N2 atmosphere. The Zn-SPAC samples were measured physicochemical characteristics such as X-ray patterns, SEM image, energy dispersive X-ray spectra, BET specific surface area, intensity and zinc content and used to remove humic acid(HA) in batch reactor for measuring photochemical activity. The X-ray patterns were appeared ZnS type. The Zn-SPAC had large BET specific surface area and their shape was spherical with a diameter about 350 - 400 μm. When the Zn-SPAC were dosed in UV reactor, the HA removal efficiency increased upto 60 % at 4hr. The order hand, the HA removal efficiency by only UV-C(λmax = 254nm) irradiation was not good about 15 %. Therefore, we infer that the Zn-SPAC have good photochemical activity and presented possibility of photocatalyst for water purification.

AB - In this study, spherical activated carbons contained ZnS(Zn-SPAC) were successfully prepared through carbonization/activation processes. Strong acid ion exchange resin as starting material of Zn-SPAC was treated by 0.01 N zinc solution. Ion exchange treatment was performed from one time to three times for controling zinc content. The ion exchanged resins was activated under N 2/H2O-vapor atmosphere at 900°C for 0.5 hr following by carbonization treatment at 700°C under N2 atmosphere. The Zn-SPAC samples were measured physicochemical characteristics such as X-ray patterns, SEM image, energy dispersive X-ray spectra, BET specific surface area, intensity and zinc content and used to remove humic acid(HA) in batch reactor for measuring photochemical activity. The X-ray patterns were appeared ZnS type. The Zn-SPAC had large BET specific surface area and their shape was spherical with a diameter about 350 - 400 μm. When the Zn-SPAC were dosed in UV reactor, the HA removal efficiency increased upto 60 % at 4hr. The order hand, the HA removal efficiency by only UV-C(λmax = 254nm) irradiation was not good about 15 %. Therefore, we infer that the Zn-SPAC have good photochemical activity and presented possibility of photocatalyst for water purification.

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M3 - Conference contribution

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T3 - Materials Science Forum

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Lee JJ, Suh JK, Hong JS, Lee JM, Park JW. Physicochemical characteristics of ZnS immobilized on spherical activated carbon for removing HA(humic acid). In Eco-Materials Processing and Design IX - Selected, peer reviewed papers from 9th International Symposium on Eco-Materials Processing and Design. Trans Tech Publications Ltd. 2008. p. 37-40. (Materials Science Forum). https://doi.org/10.4028/0-87849-472-3.37