Polymer-free vertical transfer of silicon nanowires and their application to energy storage

Han Jung Kim, Jihye Lee, Sang Eon Lee, Wanjung Kim, Hwan Jin Kim, Dae Geun Choi, Jong Hyeok Park

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Silicon nanowires (SiNWs) for use as lithium-ion battery (LIB) anode materials have been studied for their one-dimensional (1D) properties and ability to accommodate large volume changes and avoid rapid capacity fading during cycling. Although the vertical transfer of SiNWs from their original substrate onto a conducting electrode is very important, to date, there has been no report of a direct integration method without polymer binders. Here, we propose for the first time a vertical transfer method for SiNWs grown on a Si substrate directly to the current-collecting electrode without using a polymer adhesive for the use as a binder-free LIB anode. The vertical SiNWs produced using a low-cost wafer-scale metal-assisted chemical etching (MaCE) process have been successfully transferred directly to a copper electrode coated with a thin Ag layer by using a simple hot pressing method. When evaluated as an LIB anode without using conventional polymeric binder and a conducting additive, the transferred vertically aligned SiNWs showed a high specific capacity (≈2150mAh g-1) and excellent rate performance. It is believed that the anode-manufacturing process is simple and fast, thus enabling a large-scale production that is of low-cost, broadly applicable, and provides new avenues for the rational engineering of Si-based electrode materials with enhanced power density and conductivity. Standing up: A fabrication method for silicon nanowire (SiNW) assemblies for lithium-ion-battery (LIB) electrodes that require no additional support or conductive materials such as polymeric binder or carbon black is reported. When evaluated as an LIB anode without using conventional polymeric binder and a conducting additive, the transferred vertically aligned SiNWs showed a high specific capacity and excellent rate performance.

Original languageEnglish
Pages (from-to)2144-2148
Number of pages5
JournalChemSusChem
Volume6
Issue number11
DOIs
Publication statusPublished - 2013 Nov 1

Fingerprint

Silicon
Energy storage
silicon
Nanowires
Polymers
polymer
lithium
Binders
Anodes
electrode
Electrodes
ion
Soot
substrate
Conductive materials
etching
volume change
Substrates
Hot pressing
black carbon

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)

Cite this

Kim, Han Jung ; Lee, Jihye ; Lee, Sang Eon ; Kim, Wanjung ; Kim, Hwan Jin ; Choi, Dae Geun ; Park, Jong Hyeok. / Polymer-free vertical transfer of silicon nanowires and their application to energy storage. In: ChemSusChem. 2013 ; Vol. 6, No. 11. pp. 2144-2148.
@article{7710f632b3194188b011235e7abff307,
title = "Polymer-free vertical transfer of silicon nanowires and their application to energy storage",
abstract = "Silicon nanowires (SiNWs) for use as lithium-ion battery (LIB) anode materials have been studied for their one-dimensional (1D) properties and ability to accommodate large volume changes and avoid rapid capacity fading during cycling. Although the vertical transfer of SiNWs from their original substrate onto a conducting electrode is very important, to date, there has been no report of a direct integration method without polymer binders. Here, we propose for the first time a vertical transfer method for SiNWs grown on a Si substrate directly to the current-collecting electrode without using a polymer adhesive for the use as a binder-free LIB anode. The vertical SiNWs produced using a low-cost wafer-scale metal-assisted chemical etching (MaCE) process have been successfully transferred directly to a copper electrode coated with a thin Ag layer by using a simple hot pressing method. When evaluated as an LIB anode without using conventional polymeric binder and a conducting additive, the transferred vertically aligned SiNWs showed a high specific capacity (≈2150mAh g-1) and excellent rate performance. It is believed that the anode-manufacturing process is simple and fast, thus enabling a large-scale production that is of low-cost, broadly applicable, and provides new avenues for the rational engineering of Si-based electrode materials with enhanced power density and conductivity. Standing up: A fabrication method for silicon nanowire (SiNW) assemblies for lithium-ion-battery (LIB) electrodes that require no additional support or conductive materials such as polymeric binder or carbon black is reported. When evaluated as an LIB anode without using conventional polymeric binder and a conducting additive, the transferred vertically aligned SiNWs showed a high specific capacity and excellent rate performance.",
author = "Kim, {Han Jung} and Jihye Lee and Lee, {Sang Eon} and Wanjung Kim and Kim, {Hwan Jin} and Choi, {Dae Geun} and Park, {Jong Hyeok}",
year = "2013",
month = "11",
day = "1",
doi = "10.1002/cssc.201300202",
language = "English",
volume = "6",
pages = "2144--2148",
journal = "ChemSusChem",
issn = "1864-5631",
publisher = "Wiley-VCH Verlag",
number = "11",

}

Polymer-free vertical transfer of silicon nanowires and their application to energy storage. / Kim, Han Jung; Lee, Jihye; Lee, Sang Eon; Kim, Wanjung; Kim, Hwan Jin; Choi, Dae Geun; Park, Jong Hyeok.

In: ChemSusChem, Vol. 6, No. 11, 01.11.2013, p. 2144-2148.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Polymer-free vertical transfer of silicon nanowires and their application to energy storage

AU - Kim, Han Jung

AU - Lee, Jihye

AU - Lee, Sang Eon

AU - Kim, Wanjung

AU - Kim, Hwan Jin

AU - Choi, Dae Geun

AU - Park, Jong Hyeok

PY - 2013/11/1

Y1 - 2013/11/1

N2 - Silicon nanowires (SiNWs) for use as lithium-ion battery (LIB) anode materials have been studied for their one-dimensional (1D) properties and ability to accommodate large volume changes and avoid rapid capacity fading during cycling. Although the vertical transfer of SiNWs from their original substrate onto a conducting electrode is very important, to date, there has been no report of a direct integration method without polymer binders. Here, we propose for the first time a vertical transfer method for SiNWs grown on a Si substrate directly to the current-collecting electrode without using a polymer adhesive for the use as a binder-free LIB anode. The vertical SiNWs produced using a low-cost wafer-scale metal-assisted chemical etching (MaCE) process have been successfully transferred directly to a copper electrode coated with a thin Ag layer by using a simple hot pressing method. When evaluated as an LIB anode without using conventional polymeric binder and a conducting additive, the transferred vertically aligned SiNWs showed a high specific capacity (≈2150mAh g-1) and excellent rate performance. It is believed that the anode-manufacturing process is simple and fast, thus enabling a large-scale production that is of low-cost, broadly applicable, and provides new avenues for the rational engineering of Si-based electrode materials with enhanced power density and conductivity. Standing up: A fabrication method for silicon nanowire (SiNW) assemblies for lithium-ion-battery (LIB) electrodes that require no additional support or conductive materials such as polymeric binder or carbon black is reported. When evaluated as an LIB anode without using conventional polymeric binder and a conducting additive, the transferred vertically aligned SiNWs showed a high specific capacity and excellent rate performance.

AB - Silicon nanowires (SiNWs) for use as lithium-ion battery (LIB) anode materials have been studied for their one-dimensional (1D) properties and ability to accommodate large volume changes and avoid rapid capacity fading during cycling. Although the vertical transfer of SiNWs from their original substrate onto a conducting electrode is very important, to date, there has been no report of a direct integration method without polymer binders. Here, we propose for the first time a vertical transfer method for SiNWs grown on a Si substrate directly to the current-collecting electrode without using a polymer adhesive for the use as a binder-free LIB anode. The vertical SiNWs produced using a low-cost wafer-scale metal-assisted chemical etching (MaCE) process have been successfully transferred directly to a copper electrode coated with a thin Ag layer by using a simple hot pressing method. When evaluated as an LIB anode without using conventional polymeric binder and a conducting additive, the transferred vertically aligned SiNWs showed a high specific capacity (≈2150mAh g-1) and excellent rate performance. It is believed that the anode-manufacturing process is simple and fast, thus enabling a large-scale production that is of low-cost, broadly applicable, and provides new avenues for the rational engineering of Si-based electrode materials with enhanced power density and conductivity. Standing up: A fabrication method for silicon nanowire (SiNW) assemblies for lithium-ion-battery (LIB) electrodes that require no additional support or conductive materials such as polymeric binder or carbon black is reported. When evaluated as an LIB anode without using conventional polymeric binder and a conducting additive, the transferred vertically aligned SiNWs showed a high specific capacity and excellent rate performance.

UR - http://www.scopus.com/inward/record.url?scp=84887535205&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84887535205&partnerID=8YFLogxK

U2 - 10.1002/cssc.201300202

DO - 10.1002/cssc.201300202

M3 - Article

C2 - 24039099

AN - SCOPUS:84887535205

VL - 6

SP - 2144

EP - 2148

JO - ChemSusChem

JF - ChemSusChem

SN - 1864-5631

IS - 11

ER -