Polyoxometalates made of gold: The polyoxoaurate [AuIII 4Asv4O20]8-

Natalya V. Izarova; Nina Vankova; Thomas Heine; Rosa Ngo Biboum; Bineta Keita; Louis Nadjo; Ulrich Kortz

doi:10.1002/anie.200905566

Polyoxometalates made of gold: The polyoxoaurate [Au^III ₄As^v₄O₂₀]^8-

Natalya V. Izarova, Nina Vankova, Thomas Heine, Rosa Ngo Biboum, Bineta Keita, Louis Nadjo, Ulrich Kortz

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

(Figure Presented) More noble than ever: The first fully inorganic discrete polynuclear gold (III) oxo complex [Au^III₄AsV ₄O₂₀]^8- (see structure; Au yellow, As blue, O red) was prepared by condensation Of[Au(OH)⁴]^- in the presence of AsO^3-₂ ions under mild reaction conditions. The resulting polyoxoaurate exhibits a tetramerlc structure with square-planar coordinated Au^III ions linked by oxo and arsenate bridging ligands.

Original language	English
Pages (from-to)	1886-1889
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	10
DOIs	https://doi.org/10.1002/anie.200905566
Publication status	Published - 2010 Mar 1

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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title = "Polyoxometalates made of gold: The polyoxoaurate [AuIII 4Asv4O20]8-",

abstract = "(Figure Presented) More noble than ever: The first fully inorganic discrete polynuclear gold (III) oxo complex [AuIII4AsV 4O20]8- (see structure; Au yellow, As blue, O red) was prepared by condensation Of[Au(OH)4]- in the presence of AsO3-2 ions under mild reaction conditions. The resulting polyoxoaurate exhibits a tetramerlc structure with square-planar coordinated AuIII ions linked by oxo and arsenate bridging ligands.",

author = "Izarova, {Natalya V.} and Nina Vankova and Thomas Heine and Biboum, {Rosa Ngo} and Bineta Keita and Louis Nadjo and Ulrich Kortz",

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T1 - Polyoxometalates made of gold

T2 - The polyoxoaurate [AuIII 4Asv4O20]8-

AU - Izarova, Natalya V.

AU - Vankova, Nina

AU - Heine, Thomas

AU - Biboum, Rosa Ngo

AU - Keita, Bineta

AU - Nadjo, Louis

AU - Kortz, Ulrich

PY - 2010/3/1

Y1 - 2010/3/1

N2 - (Figure Presented) More noble than ever: The first fully inorganic discrete polynuclear gold (III) oxo complex [AuIII4AsV 4O20]8- (see structure; Au yellow, As blue, O red) was prepared by condensation Of[Au(OH)4]- in the presence of AsO3-2 ions under mild reaction conditions. The resulting polyoxoaurate exhibits a tetramerlc structure with square-planar coordinated AuIII ions linked by oxo and arsenate bridging ligands.

AB - (Figure Presented) More noble than ever: The first fully inorganic discrete polynuclear gold (III) oxo complex [AuIII4AsV 4O20]8- (see structure; Au yellow, As blue, O red) was prepared by condensation Of[Au(OH)4]- in the presence of AsO3-2 ions under mild reaction conditions. The resulting polyoxoaurate exhibits a tetramerlc structure with square-planar coordinated AuIII ions linked by oxo and arsenate bridging ligands.

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JO - Angewandte Chemie - International Edition

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Polyoxometalates made of gold: The polyoxoaurate [Au^III ₄As^v₄O₂₀]^8-

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