TY - JOUR
T1 - Polyoxometalates made of gold
T2 - The polyoxoaurate [AuIII 4Asv4O20]8-
AU - Izarova, Natalya V.
AU - Vankova, Nina
AU - Heine, Thomas
AU - Biboum, Rosa Ngo
AU - Keita, Bineta
AU - Nadjo, Louis
AU - Kortz, Ulrich
PY - 2010/3/1
Y1 - 2010/3/1
N2 - (Figure Presented) More noble than ever: The first fully inorganic discrete polynuclear gold (III) oxo complex [AuIII4AsV 4O20]8- (see structure; Au yellow, As blue, O red) was prepared by condensation Of[Au(OH)4]- in the presence of AsO3-2 ions under mild reaction conditions. The resulting polyoxoaurate exhibits a tetramerlc structure with square-planar coordinated AuIII ions linked by oxo and arsenate bridging ligands.
AB - (Figure Presented) More noble than ever: The first fully inorganic discrete polynuclear gold (III) oxo complex [AuIII4AsV 4O20]8- (see structure; Au yellow, As blue, O red) was prepared by condensation Of[Au(OH)4]- in the presence of AsO3-2 ions under mild reaction conditions. The resulting polyoxoaurate exhibits a tetramerlc structure with square-planar coordinated AuIII ions linked by oxo and arsenate bridging ligands.
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U2 - 10.1002/anie.200905566
DO - 10.1002/anie.200905566
M3 - Article
C2 - 20166116
AN - SCOPUS:77749240453
VL - 49
SP - 1886
EP - 1889
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 10
ER -