Polyoxometalates made of gold: The polyoxoaurate [AuIII 4Asv4O20]8-

Natalya V. Izarova, Nina Vankova, Thomas Heine, Rosa Ngo Biboum, Bineta Keita, Louis Nadjo, Ulrich Kortz

Research output: Contribution to journalArticlepeer-review

62 Citations (Scopus)

Abstract

(Figure Presented) More noble than ever: The first fully inorganic discrete polynuclear gold (III) oxo complex [AuIII4AsV 4O20]8- (see structure; Au yellow, As blue, O red) was prepared by condensation Of[Au(OH)4]- in the presence of AsO3-2 ions under mild reaction conditions. The resulting polyoxoaurate exhibits a tetramerlc structure with square-planar coordinated AuIII ions linked by oxo and arsenate bridging ligands.

Original languageEnglish
Pages (from-to)1886-1889
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number10
DOIs
Publication statusPublished - 2010 Mar 1

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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