As an alternative to oxidative acid treatment, a hydrophobic graphitized carbon nanotube (CNT) was functionalized with 1-4 nm thick polypyrrole (PPy) prior to application as catalyst supports in polymer electrolyte membrane (PEM) fuel cells. Unlike oxidative acid treatment, the PPy coating method converts the hydrophobic surface of a CNT to a hydrophilic one without creating defects on the surface of the CNT. As a result, Pt nanoparticles deposited on the PPy-coated CNTs showed an improved distribution, which significantly enhanced the fuel cell performance while preserving the intrinsic properties of the CNTs, i.e., resistance to electrochemical carbon corrosion. An additional advantage of PPy coating is that it prevents Pt nanoparticles from agglomerating on the CNT surface. These results indicated that PPy-coated CNTs are a promising catalyst support to improve both the performance and durability of PEM fuel cells.
Bibliographical noteFunding Information:
This work was supported by the New & Renewable Energy R&D program ( 2009T100100606 ) under the Ministry of Knowledge Economy, Republic of Korea and the National Research Foundation of Korea ( NRF-2009-C1AAA001-0092926 ), funded by the Ministry of Education, Science and Technology .
All Science Journal Classification (ASJC) codes
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Condensed Matter Physics
- Energy Engineering and Power Technology