Porphyrin-hexaphyrin hybrid tapes

Takayuki Tanaka, Naoki Aratani, Jong Min Lim, Kil Suk Kim, Dongho Kim, Atsuhiro Osuka

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46 Citations (Scopus)

Abstract

A meso-meso linked porphyrin-hexaphyrin hybrid was synthesized by the cross condensation using meso-porphyrinyl-dipyrromethane and was oxidized with DDQ-Sc(OTf)3 to afford a porphyrin-[26] hexaphyrin hybrid tape that was reduced with NaBH4 to give a porphyrin-[28]hexaphyrin hybrid tape. Fully electronic conjugations in the hybrid tapes are observed in the UV/vis/NIR absorption spectra, electrochemistry, and excited-state dynamics.

Original languageEnglish
Pages (from-to)1414-1418
Number of pages5
JournalChemical Science
Volume2
Issue number7
DOIs
Publication statusPublished - 2011 Jul

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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  • Cite this

    Tanaka, T., Aratani, N., Lim, J. M., Kim, K. S., Kim, D., & Osuka, A. (2011). Porphyrin-hexaphyrin hybrid tapes. Chemical Science, 2(7), 1414-1418. https://doi.org/10.1039/c1sc00228g