Porphyrin-Ryleneimide Hybrids: Low-Bandgap Acceptors in Energy-Transfer Cassettes

Ewelina Janiga, Gakhyun Kim, Piotr J. Chmielewski, Tadeusz Lis, Dongho Kim, Marcin Stępień

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Energy-transfer cassettes consisting of naphthaleneimide-fused metalloporphyrin acceptors (M=Zn and Pd) and BODIPY donors have been designed and synthesized. These systems have rigid pseudo-tetrahedral structures with a donor-acceptor separation of ca. 17.5 Å. Spectroscopic investigations, including femtosecond transient absorption measurements, showed efficient excitation energy transfer (EET) occurring according to the Förster mechanism. Strong fluorescence of the donor units and significant spectral overlap of the donor and acceptor subunits are prerequisites for the efficient EET in these systems.

Original languageEnglish
Pages (from-to)2854-2858
Number of pages5
JournalChemistry - An Asian Journal
Volume15
Issue number18
DOIs
Publication statusPublished - 2020 Sep 15

Bibliographical note

Funding Information:
Financial support from the Foundation for Polish Science (TEAM POIR.04.04.00‐00‐5BF1/17‐00 for M.S.) is gratefully acknowledged. Computational work was performed at the Wrocław Center for Supercomputing. The work at Yonsei University was supported by Strategic Research (NRF2016R1E1A1A01943379) through the National Research Foundation of Korea (NRF) funded by the Ministry of Science.

Publisher Copyright:
© 2020 Wiley-VCH GmbH

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Organic Chemistry

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