Position-controlled hydrothermal growth of ZnO nanorods on arbitrary substrates with a patterned seed layer via ultraviolet-assisted nanoimprint lithography

Hyeong Ho Park, Xin Zhang, Keun Woo Lee, Ka Hee Kim, Sang Hyun Jung, Deok Soo Park, Young Su Choi, Hyun Beom Shin, Ho Kun Sung, Kyung Ho Park, Ho Kwan Kang, Hyung-Ho Park, Chul Ki Ko

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

A novel technique for the position-controlled growth of ZnO nanorods is established, by combining ultraviolet-assisted nanoimprint lithography (UV-NIL) and hydrothermal growth. Various ZnO nanorod arrays were obtained on silicon substrates, by UV-NIL of ZnO seed patterns with lines of 200 nm wide at a pitch of 1000 nm from a photosensitive ZnO precursor, followed by a position-controlled hydrothermal growth step with varied growth times. It was found that the aspect ratio of ZnO nanorods increased from 2.7 to 11.8 as the growth time was increased from 2 to 6 h. Selected area electron diffraction (SAED) analysis indicates that the root of studied ZnO nanorods consists of both amorphous and polycrystalline phases whereas the stem shows a single-crystalline nature with a preferred (002) growth. ZnO nanorod arrays were also routinely obtained on transparent glass and flexible polyethylene terephthalate (PET). In all cases, ZnO nanorods were observed on both the sidewalls and top surfaces of the ZnO seed patterns with a nanoflower-like structure regardless of substrate substances. This technique offers an alternative method for integrating ZnO nanorods at low temperatures and free of high vacuum, potentially useful in applications such as nanophotonics, photovoltaics and flexible nanoelectronics.

Original languageEnglish
Pages (from-to)3463-3469
Number of pages7
JournalCrystEngComm
Volume15
Issue number17
DOIs
Publication statusPublished - 2013 May 7

Fingerprint

Nanoimprint lithography
Nanorods
nanorods
Seed
seeds
lithography
Substrates
Nanoflowers
Nanophotonics
Polyethylene Terephthalates
Nanoelectronics
polyethylene terephthalate
Silicon
high vacuum
stems
Electron diffraction
Polyethylene terephthalates
aspect ratio
Aspect ratio
electron diffraction

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Park, Hyeong Ho ; Zhang, Xin ; Lee, Keun Woo ; Kim, Ka Hee ; Jung, Sang Hyun ; Park, Deok Soo ; Choi, Young Su ; Shin, Hyun Beom ; Sung, Ho Kun ; Park, Kyung Ho ; Kang, Ho Kwan ; Park, Hyung-Ho ; Ko, Chul Ki. / Position-controlled hydrothermal growth of ZnO nanorods on arbitrary substrates with a patterned seed layer via ultraviolet-assisted nanoimprint lithography. In: CrystEngComm. 2013 ; Vol. 15, No. 17. pp. 3463-3469.
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abstract = "A novel technique for the position-controlled growth of ZnO nanorods is established, by combining ultraviolet-assisted nanoimprint lithography (UV-NIL) and hydrothermal growth. Various ZnO nanorod arrays were obtained on silicon substrates, by UV-NIL of ZnO seed patterns with lines of 200 nm wide at a pitch of 1000 nm from a photosensitive ZnO precursor, followed by a position-controlled hydrothermal growth step with varied growth times. It was found that the aspect ratio of ZnO nanorods increased from 2.7 to 11.8 as the growth time was increased from 2 to 6 h. Selected area electron diffraction (SAED) analysis indicates that the root of studied ZnO nanorods consists of both amorphous and polycrystalline phases whereas the stem shows a single-crystalline nature with a preferred (002) growth. ZnO nanorod arrays were also routinely obtained on transparent glass and flexible polyethylene terephthalate (PET). In all cases, ZnO nanorods were observed on both the sidewalls and top surfaces of the ZnO seed patterns with a nanoflower-like structure regardless of substrate substances. This technique offers an alternative method for integrating ZnO nanorods at low temperatures and free of high vacuum, potentially useful in applications such as nanophotonics, photovoltaics and flexible nanoelectronics.",
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Park, HH, Zhang, X, Lee, KW, Kim, KH, Jung, SH, Park, DS, Choi, YS, Shin, HB, Sung, HK, Park, KH, Kang, HK, Park, H-H & Ko, CK 2013, 'Position-controlled hydrothermal growth of ZnO nanorods on arbitrary substrates with a patterned seed layer via ultraviolet-assisted nanoimprint lithography', CrystEngComm, vol. 15, no. 17, pp. 3463-3469. https://doi.org/10.1039/c3ce27069f

Position-controlled hydrothermal growth of ZnO nanorods on arbitrary substrates with a patterned seed layer via ultraviolet-assisted nanoimprint lithography. / Park, Hyeong Ho; Zhang, Xin; Lee, Keun Woo; Kim, Ka Hee; Jung, Sang Hyun; Park, Deok Soo; Choi, Young Su; Shin, Hyun Beom; Sung, Ho Kun; Park, Kyung Ho; Kang, Ho Kwan; Park, Hyung-Ho; Ko, Chul Ki.

In: CrystEngComm, Vol. 15, No. 17, 07.05.2013, p. 3463-3469.

Research output: Contribution to journalArticle

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T1 - Position-controlled hydrothermal growth of ZnO nanorods on arbitrary substrates with a patterned seed layer via ultraviolet-assisted nanoimprint lithography

AU - Park, Hyeong Ho

AU - Zhang, Xin

AU - Lee, Keun Woo

AU - Kim, Ka Hee

AU - Jung, Sang Hyun

AU - Park, Deok Soo

AU - Choi, Young Su

AU - Shin, Hyun Beom

AU - Sung, Ho Kun

AU - Park, Kyung Ho

AU - Kang, Ho Kwan

AU - Park, Hyung-Ho

AU - Ko, Chul Ki

PY - 2013/5/7

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N2 - A novel technique for the position-controlled growth of ZnO nanorods is established, by combining ultraviolet-assisted nanoimprint lithography (UV-NIL) and hydrothermal growth. Various ZnO nanorod arrays were obtained on silicon substrates, by UV-NIL of ZnO seed patterns with lines of 200 nm wide at a pitch of 1000 nm from a photosensitive ZnO precursor, followed by a position-controlled hydrothermal growth step with varied growth times. It was found that the aspect ratio of ZnO nanorods increased from 2.7 to 11.8 as the growth time was increased from 2 to 6 h. Selected area electron diffraction (SAED) analysis indicates that the root of studied ZnO nanorods consists of both amorphous and polycrystalline phases whereas the stem shows a single-crystalline nature with a preferred (002) growth. ZnO nanorod arrays were also routinely obtained on transparent glass and flexible polyethylene terephthalate (PET). In all cases, ZnO nanorods were observed on both the sidewalls and top surfaces of the ZnO seed patterns with a nanoflower-like structure regardless of substrate substances. This technique offers an alternative method for integrating ZnO nanorods at low temperatures and free of high vacuum, potentially useful in applications such as nanophotonics, photovoltaics and flexible nanoelectronics.

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