Preparation and characterization of LDPE/PVA blend films filled with glycerin-plasticized polyvinyl alcohol

Dowan Kim; Jeyoung Jung; Su Il Park; Jongchul Seo

doi:10.1002/app.41985

Preparation and characterization of LDPE/PVA blend films filled with glycerin-plasticized polyvinyl alcohol

Dowan Kim, Jeyoung Jung, Su Il Park, Jongchul Seo

Packaging

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A series of LDPE/PVA blend films were prepared via a twin-screw extruder, and their morphology, thermal property, oxygen and water vapor permeation, surface properties, and mechanical properties were investigated as a function of the PVA content. During the extrusion process of the blend films, glycerin improved the compatibility and processing conditions between LDPE and PVA. The melting temperature (T_m), melting enthalpy (ΔH_m), crystallinity (%), and thermal stability of the thermal decomposition temperature (T_5%) of the LDPE/PVA blend films decreased with increasing PVA content. The oxygen permeabilities of the blend films decreased from 24.0 to 11.4 cm³·cm (m²·day·atm)^-¹ at 23°C. The WVTR increased from 7.8 to 15.0 g(m² day)^-1 and the water uptake increased from 0.13 to 9.31%, respectively. The mechanical properties of blend films were slightly enhanced up to 2% PVA and then decreased. The physical properties of the blend films strongly varied with the chemical structure and morphology depending on the PVA and glycerin.

Original language	English
Article number	41985
Journal	Journal of Applied Polymer Science
Volume	132
Issue number	22
DOIs	https://doi.org/10.1002/app.41985
Publication status	Published - 2015 Jun 1

Bibliographical note

Publisher Copyright:
© 2015 Wiley Periodicals, Inc.

All Science Journal Classification (ASJC) codes

Chemistry(all)
Surfaces, Coatings and Films
Polymers and Plastics
Materials Chemistry

Access to Document

10.1002/app.41985

Cite this

@article{6e9d2bb093c2444da34c758ae8410d18,

title = "Preparation and characterization of LDPE/PVA blend films filled with glycerin-plasticized polyvinyl alcohol",

abstract = "A series of LDPE/PVA blend films were prepared via a twin-screw extruder, and their morphology, thermal property, oxygen and water vapor permeation, surface properties, and mechanical properties were investigated as a function of the PVA content. During the extrusion process of the blend films, glycerin improved the compatibility and processing conditions between LDPE and PVA. The melting temperature (Tm), melting enthalpy (ΔHm), crystallinity (%), and thermal stability of the thermal decomposition temperature (T5%) of the LDPE/PVA blend films decreased with increasing PVA content. The oxygen permeabilities of the blend films decreased from 24.0 to 11.4 cm3·cm (m2·day·atm)-1 at 23°C. The WVTR increased from 7.8 to 15.0 g(m2 day)-1 and the water uptake increased from 0.13 to 9.31%, respectively. The mechanical properties of blend films were slightly enhanced up to 2% PVA and then decreased. The physical properties of the blend films strongly varied with the chemical structure and morphology depending on the PVA and glycerin.",

author = "Dowan Kim and Jeyoung Jung and Park, {Su Il} and Jongchul Seo",

note = "Publisher Copyright: {\textcopyright} 2015 Wiley Periodicals, Inc.",

year = "2015",

month = jun,

day = "1",

doi = "10.1002/app.41985",

language = "English",

volume = "132",

journal = "Journal of Applied Polymer Science",

issn = "0021-8995",

publisher = "John Wiley and Sons Inc.",

number = "22",

}

TY - JOUR

T1 - Preparation and characterization of LDPE/PVA blend films filled with glycerin-plasticized polyvinyl alcohol

AU - Kim, Dowan

AU - Jung, Jeyoung

AU - Park, Su Il

AU - Seo, Jongchul

PY - 2015/6/1

Y1 - 2015/6/1

N2 - A series of LDPE/PVA blend films were prepared via a twin-screw extruder, and their morphology, thermal property, oxygen and water vapor permeation, surface properties, and mechanical properties were investigated as a function of the PVA content. During the extrusion process of the blend films, glycerin improved the compatibility and processing conditions between LDPE and PVA. The melting temperature (Tm), melting enthalpy (ΔHm), crystallinity (%), and thermal stability of the thermal decomposition temperature (T5%) of the LDPE/PVA blend films decreased with increasing PVA content. The oxygen permeabilities of the blend films decreased from 24.0 to 11.4 cm3·cm (m2·day·atm)-1 at 23°C. The WVTR increased from 7.8 to 15.0 g(m2 day)-1 and the water uptake increased from 0.13 to 9.31%, respectively. The mechanical properties of blend films were slightly enhanced up to 2% PVA and then decreased. The physical properties of the blend films strongly varied with the chemical structure and morphology depending on the PVA and glycerin.

AB - A series of LDPE/PVA blend films were prepared via a twin-screw extruder, and their morphology, thermal property, oxygen and water vapor permeation, surface properties, and mechanical properties were investigated as a function of the PVA content. During the extrusion process of the blend films, glycerin improved the compatibility and processing conditions between LDPE and PVA. The melting temperature (Tm), melting enthalpy (ΔHm), crystallinity (%), and thermal stability of the thermal decomposition temperature (T5%) of the LDPE/PVA blend films decreased with increasing PVA content. The oxygen permeabilities of the blend films decreased from 24.0 to 11.4 cm3·cm (m2·day·atm)-1 at 23°C. The WVTR increased from 7.8 to 15.0 g(m2 day)-1 and the water uptake increased from 0.13 to 9.31%, respectively. The mechanical properties of blend films were slightly enhanced up to 2% PVA and then decreased. The physical properties of the blend films strongly varied with the chemical structure and morphology depending on the PVA and glycerin.

UR - http://www.scopus.com/inward/record.url?scp=84924496972&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84924496972&partnerID=8YFLogxK

U2 - 10.1002/app.41985

DO - 10.1002/app.41985

M3 - Article

AN - SCOPUS:84924496972

VL - 132

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

SN - 0021-8995

IS - 22

M1 - 41985

ER -

Preparation and characterization of LDPE/PVA blend films filled with glycerin-plasticized polyvinyl alcohol

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this