Abstract
Spherical porous polymer particles with high surface area were synthesized using the water-in-oil-inwater (W/O/W) emulsion polymerization and Friedel-Crafts reaction. After the preparation of W/O emulsions, spherical porous polymer particles were synthesized by suspension polymerization. Spherical porous polymer precursor particles were subjected to Friedel-Crafts reaction using a Lewis acid catalyst. The properties of the final products synthesized with different porogen contents in the water-in-oil (W/O) emulsion were explored. The Friedel-Crafts reaction was used to increase the Brunauer-Emmett-Teller (BET) surface area. In order to identify the effects of the porogen levels and of the Friedel-Crafts reaction, the synthesized porous particles were analyzed by particle size analyzer (PSA), Hg porosimetry, and the BET surface area method. In addition, the morphology of the particles was investigated by FE-SEM. [Figure not available: see fulltext.]
| Original language | English |
|---|---|
| Pages (from-to) | 1051-1058 |
| Number of pages | 8 |
| Journal | Macromolecular Research |
| Volume | 23 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 2015 Nov 1 |
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All Science Journal Classification (ASJC) codes
- Chemical Engineering(all)
- Organic Chemistry
- Polymers and Plastics
- Materials Chemistry
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Preparation of hypercrosslinked poly(DVB-VBC) particles with high surface area and structured meso- and micropores. / Hwang, Ki Seob; Choi, Won Jun; Kim, Jung-Hyun; Lee, Jun Young.
In: Macromolecular Research, Vol. 23, No. 11, 01.11.2015, p. 1051-1058.Research output: Contribution to journal › Article
TY - JOUR
T1 - Preparation of hypercrosslinked poly(DVB-VBC) particles with high surface area and structured meso- and micropores
AU - Hwang, Ki Seob
AU - Choi, Won Jun
AU - Kim, Jung-Hyun
AU - Lee, Jun Young
PY - 2015/11/1
Y1 - 2015/11/1
N2 - Spherical porous polymer particles with high surface area were synthesized using the water-in-oil-inwater (W/O/W) emulsion polymerization and Friedel-Crafts reaction. After the preparation of W/O emulsions, spherical porous polymer particles were synthesized by suspension polymerization. Spherical porous polymer precursor particles were subjected to Friedel-Crafts reaction using a Lewis acid catalyst. The properties of the final products synthesized with different porogen contents in the water-in-oil (W/O) emulsion were explored. The Friedel-Crafts reaction was used to increase the Brunauer-Emmett-Teller (BET) surface area. In order to identify the effects of the porogen levels and of the Friedel-Crafts reaction, the synthesized porous particles were analyzed by particle size analyzer (PSA), Hg porosimetry, and the BET surface area method. In addition, the morphology of the particles was investigated by FE-SEM. [Figure not available: see fulltext.]
AB - Spherical porous polymer particles with high surface area were synthesized using the water-in-oil-inwater (W/O/W) emulsion polymerization and Friedel-Crafts reaction. After the preparation of W/O emulsions, spherical porous polymer particles were synthesized by suspension polymerization. Spherical porous polymer precursor particles were subjected to Friedel-Crafts reaction using a Lewis acid catalyst. The properties of the final products synthesized with different porogen contents in the water-in-oil (W/O) emulsion were explored. The Friedel-Crafts reaction was used to increase the Brunauer-Emmett-Teller (BET) surface area. In order to identify the effects of the porogen levels and of the Friedel-Crafts reaction, the synthesized porous particles were analyzed by particle size analyzer (PSA), Hg porosimetry, and the BET surface area method. In addition, the morphology of the particles was investigated by FE-SEM. [Figure not available: see fulltext.]
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U2 - 10.1007/s13233-015-3137-7
DO - 10.1007/s13233-015-3137-7
M3 - Article
VL - 23
SP - 1051
EP - 1058
JO - Macromolecular Research
JF - Macromolecular Research
SN - 1598-5032
IS - 11
ER -