Preparation of monodisperse melamine-formaldehyde microspheres via dispersed polycondensation

In Woo Cheong, Jin Sup Shin, Jung Hyun Kim, Seung Jun Lee

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

We have successfully synthesized relatively monodisperse and cross-linked melamine-formaldehyde (M-F) microspheres by dispersed polycondensation and subsequent pH adjustment with serum replacement cleaning. The average particle sizes (D̄w: weight-average and D̄n: number-average), the polydispersity index (D̄w/D̄ n), the number of particles Np, and the gel content of the M-F microspheres were observed by varying the pH, the surfactant concentration, and the polymerization temperature. We observed that both the pH and the polymerization temperature were predominant factors in determining D̄n and Np, but the effect that the temperature and pH had on the gel content (> 94% for all samples) was negligible. The exponents of the slopes of plots of Np, versus pH and surfactant concentration were -10 and 0.6, respectively. Particle nucleation and growth were achieved within short periods; the incessant coagulation occurred even in the presence of surfactants.

Original languageEnglish
Pages (from-to)225-232
Number of pages8
JournalMacromolecular Research
Volume12
Issue number2
DOIs
Publication statusPublished - 2004 Apr

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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