Preparation of TiO2/Ag binary nanocomposite as high-activity visible-light-driven photocatalyst via graft polymerization

Jung Tae Park; Chang Soo Lee; Cheol Hun Park; Jong Hak Kim

doi:10.1016/j.cplett.2017.07.054

Preparation of TiO₂/Ag binary nanocomposite as high-activity visible-light-driven photocatalyst via graft polymerization

Jung Tae Park, Chang Soo Lee, Cheol Hun Park, Jong Hak Kim

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

We report the synthesis of a TiO₂/Ag binary nanocomposite with high activity for visible-light-driven photocatalysts using graft copolymerization: (1) conversion of terminal OH groups on the surface of TiO₂ nanoparticles to Cl groups, (2) graft polymerization from TiO₂–Cl via ATRP with ionically charged poly(styrene sulfonic acid), (3) ion exchange process with an AgNO₃ solution following sintering. TiO2/Ag binary nanocomposite showed enhanced photocatalytic performance for the degradation of methyl orange under visible light illumination. The improved photocatalytic performance of the TiO₂/Ag binary nanocomposite was due to the plasmonic effect, recombination rate of electron–hole pairs that was suppressed by Ag nanoparticles.

Original language	English
Pages (from-to)	119-126
Number of pages	8
Journal	Chemical Physics Letters
Volume	685
DOIs	https://doi.org/10.1016/j.cplett.2017.07.054
Publication status	Published - 2017

Bibliographical note

Publisher Copyright:
© 2017

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1016/j.cplett.2017.07.054

Fingerprint Dive into the research topics of 'Preparation of TiO<sub>2</sub>/Ag binary nanocomposite as high-activity visible-light-driven photocatalyst via graft polymerization'. Together they form a unique fingerprint.

Cite this

@article{bbc20d57a67a4333a8e2c911fd13af1f,

title = "Preparation of TiO2/Ag binary nanocomposite as high-activity visible-light-driven photocatalyst via graft polymerization",

abstract = "We report the synthesis of a TiO2/Ag binary nanocomposite with high activity for visible-light-driven photocatalysts using graft copolymerization: (1) conversion of terminal OH groups on the surface of TiO2 nanoparticles to Cl groups, (2) graft polymerization from TiO2–Cl via ATRP with ionically charged poly(styrene sulfonic acid), (3) ion exchange process with an AgNO3 solution following sintering. TiO2/Ag binary nanocomposite showed enhanced photocatalytic performance for the degradation of methyl orange under visible light illumination. The improved photocatalytic performance of the TiO2/Ag binary nanocomposite was due to the plasmonic effect, recombination rate of electron–hole pairs that was suppressed by Ag nanoparticles.",

author = "{Tae Park}, Jung and {Soo Lee}, Chang and {Hun Park}, Cheol and {Hak Kim}, Jong",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2017",

doi = "10.1016/j.cplett.2017.07.054",

language = "English",

volume = "685",

pages = "119--126",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

}

TY - JOUR

T1 - Preparation of TiO2/Ag binary nanocomposite as high-activity visible-light-driven photocatalyst via graft polymerization

AU - Tae Park, Jung

AU - Soo Lee, Chang

AU - Hun Park, Cheol

AU - Hak Kim, Jong

PY - 2017

Y1 - 2017

N2 - We report the synthesis of a TiO2/Ag binary nanocomposite with high activity for visible-light-driven photocatalysts using graft copolymerization: (1) conversion of terminal OH groups on the surface of TiO2 nanoparticles to Cl groups, (2) graft polymerization from TiO2–Cl via ATRP with ionically charged poly(styrene sulfonic acid), (3) ion exchange process with an AgNO3 solution following sintering. TiO2/Ag binary nanocomposite showed enhanced photocatalytic performance for the degradation of methyl orange under visible light illumination. The improved photocatalytic performance of the TiO2/Ag binary nanocomposite was due to the plasmonic effect, recombination rate of electron–hole pairs that was suppressed by Ag nanoparticles.

AB - We report the synthesis of a TiO2/Ag binary nanocomposite with high activity for visible-light-driven photocatalysts using graft copolymerization: (1) conversion of terminal OH groups on the surface of TiO2 nanoparticles to Cl groups, (2) graft polymerization from TiO2–Cl via ATRP with ionically charged poly(styrene sulfonic acid), (3) ion exchange process with an AgNO3 solution following sintering. TiO2/Ag binary nanocomposite showed enhanced photocatalytic performance for the degradation of methyl orange under visible light illumination. The improved photocatalytic performance of the TiO2/Ag binary nanocomposite was due to the plasmonic effect, recombination rate of electron–hole pairs that was suppressed by Ag nanoparticles.

UR - http://www.scopus.com/inward/record.url?scp=85026201085&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85026201085&partnerID=8YFLogxK

U2 - 10.1016/j.cplett.2017.07.054

DO - 10.1016/j.cplett.2017.07.054

M3 - Article

AN - SCOPUS:85026201085

VL - 685

SP - 119

EP - 126

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

ER -