Pressure- and heat-induced insertion of CO2 into an auxetic small-pore zeolite

Yongjae Lee, Dan Liu, Donghoon Seoung, Zhenxian Liu, Chi Chang Kao, Thomas Vogt

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45 Citations (Scopus)

Abstract

When the small-pore zeolite natrolite is compressed at ca. 1.5 GPa and heated to ca. 110 °C in the presence of CO2, the unit cell volume of natrolite expands by 6.8% and ca. 12 wt % of CO2 is contained in the expanded elliptical channels. This CO2 insertion into natrolite is found to be reversible upon pressure release.

Original languageEnglish
Pages (from-to)1674-1677
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number6
DOIs
Publication statusPublished - 2011 Feb 16

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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