Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene

Different ground-state properties and applications in field-effect transistors

Xueliang Shi, Sangsu Lee, Minjung Son, Bin Zheng, Jingjing Chang, Linzhi Jing, Kuo Wei Huang, Dongho Kim, Chunyan Chi

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

A pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS.

Original languageEnglish
Pages (from-to)13178-13180
Number of pages3
JournalChemical Communications
Volume51
Issue number67
DOIs
Publication statusPublished - 2015 Jul 1

Fingerprint

Thiophenes
Thiophene
Field effect transistors
Ground state
Excited states
Oxidation-Reduction

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Shi, Xueliang ; Lee, Sangsu ; Son, Minjung ; Zheng, Bin ; Chang, Jingjing ; Jing, Linzhi ; Huang, Kuo Wei ; Kim, Dongho ; Chi, Chunyan. / Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene : Different ground-state properties and applications in field-effect transistors. In: Chemical Communications. 2015 ; Vol. 51, No. 67. pp. 13178-13180.
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abstract = "A pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS.",
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Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene : Different ground-state properties and applications in field-effect transistors. / Shi, Xueliang; Lee, Sangsu; Son, Minjung; Zheng, Bin; Chang, Jingjing; Jing, Linzhi; Huang, Kuo Wei; Kim, Dongho; Chi, Chunyan.

In: Chemical Communications, Vol. 51, No. 67, 01.07.2015, p. 13178-13180.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene

T2 - Different ground-state properties and applications in field-effect transistors

AU - Shi, Xueliang

AU - Lee, Sangsu

AU - Son, Minjung

AU - Zheng, Bin

AU - Chang, Jingjing

AU - Jing, Linzhi

AU - Huang, Kuo Wei

AU - Kim, Dongho

AU - Chi, Chunyan

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AB - A pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS.

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JF - Chemical Communications

SN - 1359-7345

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