We report the first time-resolved soft x-ray measurements of solvated transitionmetal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding.
|Title of host publication||Springer Series in Chemical Physics|
|Publisher||Springer Science and Business Media Deutschland GmbH|
|Number of pages||3|
|Publication status||Published - 2009|
|Name||Springer Series in Chemical Physics|
Bibliographical noteFunding Information:
This work was supported by the Department of Energy under Contract No. DE-AC02-05CH11231.
© 2009, Springer-Verlag Berlin Heidelberg.
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry