Protonation-triggered conformational changes to Möbius aromatic [32]heptaphyrins(1.1.1.1.1.1.1)

Shohei Saito, Jae Yoon Shin, Jong Min Lim, Kil Suk Kim, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journalArticle

109 Citations (Scopus)

Abstract

Switching Aromaticity: Conformations of [32]heptaphyrins (1.1.1.1.1.1.1) are dependent upon meso-aryl substituents, solvents, temperature, and protonation. Particularly, protonation of meso-pentafluorophenyl-substituted [32]heptaphyrin triggers conformational changes to form twisted aromatic Möbius structures (see picture), even at room temperature. (Figure Presented).

Original languageEnglish
Pages (from-to)9657-9660
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number50
DOIs
Publication statusPublished - 2008 Dec 1

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Protonation
Conformations
Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Saito, Shohei ; Shin, Jae Yoon ; Lim, Jong Min ; Kim, Kil Suk ; Kim, Dongho ; Osuka, Atsuhiro. / Protonation-triggered conformational changes to Möbius aromatic [32]heptaphyrins(1.1.1.1.1.1.1). In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 50. pp. 9657-9660.
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Protonation-triggered conformational changes to Möbius aromatic [32]heptaphyrins(1.1.1.1.1.1.1). / Saito, Shohei; Shin, Jae Yoon; Lim, Jong Min; Kim, Kil Suk; Kim, Dongho; Osuka, Atsuhiro.

In: Angewandte Chemie - International Edition, Vol. 47, No. 50, 01.12.2008, p. 9657-9660.

Research output: Contribution to journalArticle

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