Pseudocapacitive properties of nanostructured anhydrous ruthenium oxide thin film prepared by electrostatic spray deposition and electrochemical lithiation/delithiation

S. H. Park, J. Y. Kim, Kwang Bum Kim

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Abstract

Nano-structured anhydrous ruthenium oxide (RuO2) thin films were prepared using an electrostatic spray deposition (ESD) technique followed by electrochemical lithiation and delithiation. During the electrochemical lithiation process, RuO2 decomposed to nano-structured metallic ruthenium Ru with the concomitant formation of Li2O. Nano-structured RuO2 was formed upon subsequent electrochemical extraction of Li from the Ru/Li2O nanocomposite. Electrochemical lithiation/deliathiation at different charge/discharge rates (C-rate) was used to control the nano-structure of the anhydrous RuO2. Electrochemical lithiation/delithiation of the RuO2 thin film electrode at different C-rates was closely related to the specific capacitance and high rate capability of the nano-structured anhydrous RuO2 thin film. Nano-structured RuO2 thin films prepared by electrochemical lithiation and delithiation at 2C rate showed the highest specific capacitance of 653 F g -1 at 20 mV s-1, which is more than two times higher than the specific capacitance of 269 F g-1 for the as-prepared RuO 2. In addition, it showed 14% loss in specific capacitance from 653 F g-1 at 20 mV s-1 to 559 F g-1 at 200 mV s -1, indicating significant improvement in the high rate capability compared to the 26% loss of specific capacitance of the as-prepared RuO 2 electrode from 269 F g-1 at 20 mV s-1 to 198 F g-1 at 200 mV s-1 for the same change in scan rate.

Original languageEnglish
Pages (from-to)865-872
Number of pages8
JournalFuel Cells
Volume10
Issue number5
DOIs
Publication statusPublished - 2010 Jan 1

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Ruthenium
Oxide films
Electrostatics
Capacitance
Thin films
Electrodes
Nanocomposites

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology

Cite this

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title = "Pseudocapacitive properties of nanostructured anhydrous ruthenium oxide thin film prepared by electrostatic spray deposition and electrochemical lithiation/delithiation",
abstract = "Nano-structured anhydrous ruthenium oxide (RuO2) thin films were prepared using an electrostatic spray deposition (ESD) technique followed by electrochemical lithiation and delithiation. During the electrochemical lithiation process, RuO2 decomposed to nano-structured metallic ruthenium Ru with the concomitant formation of Li2O. Nano-structured RuO2 was formed upon subsequent electrochemical extraction of Li from the Ru/Li2O nanocomposite. Electrochemical lithiation/deliathiation at different charge/discharge rates (C-rate) was used to control the nano-structure of the anhydrous RuO2. Electrochemical lithiation/delithiation of the RuO2 thin film electrode at different C-rates was closely related to the specific capacitance and high rate capability of the nano-structured anhydrous RuO2 thin film. Nano-structured RuO2 thin films prepared by electrochemical lithiation and delithiation at 2C rate showed the highest specific capacitance of 653 F g -1 at 20 mV s-1, which is more than two times higher than the specific capacitance of 269 F g-1 for the as-prepared RuO 2. In addition, it showed 14{\%} loss in specific capacitance from 653 F g-1 at 20 mV s-1 to 559 F g-1 at 200 mV s -1, indicating significant improvement in the high rate capability compared to the 26{\%} loss of specific capacitance of the as-prepared RuO 2 electrode from 269 F g-1 at 20 mV s-1 to 198 F g-1 at 200 mV s-1 for the same change in scan rate.",
author = "Park, {S. H.} and Kim, {J. Y.} and Kim, {Kwang Bum}",
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T1 - Pseudocapacitive properties of nanostructured anhydrous ruthenium oxide thin film prepared by electrostatic spray deposition and electrochemical lithiation/delithiation

AU - Park, S. H.

AU - Kim, J. Y.

AU - Kim, Kwang Bum

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N2 - Nano-structured anhydrous ruthenium oxide (RuO2) thin films were prepared using an electrostatic spray deposition (ESD) technique followed by electrochemical lithiation and delithiation. During the electrochemical lithiation process, RuO2 decomposed to nano-structured metallic ruthenium Ru with the concomitant formation of Li2O. Nano-structured RuO2 was formed upon subsequent electrochemical extraction of Li from the Ru/Li2O nanocomposite. Electrochemical lithiation/deliathiation at different charge/discharge rates (C-rate) was used to control the nano-structure of the anhydrous RuO2. Electrochemical lithiation/delithiation of the RuO2 thin film electrode at different C-rates was closely related to the specific capacitance and high rate capability of the nano-structured anhydrous RuO2 thin film. Nano-structured RuO2 thin films prepared by electrochemical lithiation and delithiation at 2C rate showed the highest specific capacitance of 653 F g -1 at 20 mV s-1, which is more than two times higher than the specific capacitance of 269 F g-1 for the as-prepared RuO 2. In addition, it showed 14% loss in specific capacitance from 653 F g-1 at 20 mV s-1 to 559 F g-1 at 200 mV s -1, indicating significant improvement in the high rate capability compared to the 26% loss of specific capacitance of the as-prepared RuO 2 electrode from 269 F g-1 at 20 mV s-1 to 198 F g-1 at 200 mV s-1 for the same change in scan rate.

AB - Nano-structured anhydrous ruthenium oxide (RuO2) thin films were prepared using an electrostatic spray deposition (ESD) technique followed by electrochemical lithiation and delithiation. During the electrochemical lithiation process, RuO2 decomposed to nano-structured metallic ruthenium Ru with the concomitant formation of Li2O. Nano-structured RuO2 was formed upon subsequent electrochemical extraction of Li from the Ru/Li2O nanocomposite. Electrochemical lithiation/deliathiation at different charge/discharge rates (C-rate) was used to control the nano-structure of the anhydrous RuO2. Electrochemical lithiation/delithiation of the RuO2 thin film electrode at different C-rates was closely related to the specific capacitance and high rate capability of the nano-structured anhydrous RuO2 thin film. Nano-structured RuO2 thin films prepared by electrochemical lithiation and delithiation at 2C rate showed the highest specific capacitance of 653 F g -1 at 20 mV s-1, which is more than two times higher than the specific capacitance of 269 F g-1 for the as-prepared RuO 2. In addition, it showed 14% loss in specific capacitance from 653 F g-1 at 20 mV s-1 to 559 F g-1 at 200 mV s -1, indicating significant improvement in the high rate capability compared to the 26% loss of specific capacitance of the as-prepared RuO 2 electrode from 269 F g-1 at 20 mV s-1 to 198 F g-1 at 200 mV s-1 for the same change in scan rate.

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