Pyridine-2-thiolate bridged tin-palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

Erik Wächtler; Robert Gericke; Lyuben Zhechkov; Thomas Heine; Thorsten Langer; Birgit Gerke; Rainer Pöttgen; Jörg Wagler

doi:10.1039/c3cc47912a

Pyridine-2-thiolate bridged tin-palladium complexes with Sn(PdN₂Cl₂), Sn(PdN₂S₂), Sn(PdN₂C₂) and Sn(Pd₂N₄) skeletons

Erik Wächtler, Robert Gericke, Lyuben Zhechkov, Thomas Heine, Thorsten Langer, Birgit Gerke, Rainer Pöttgen, Jörg Wagler

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Reactions of tin(IV) complexes of the type Sn(PyS)₂X₂ (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh₃)₄ provide easy access to novel heterometallic complexes with Pd-Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, ¹¹⁹Sn Mössbauer spectroscopy and quantum chemical analyses.

Original language	English
Pages (from-to)	5382-5384
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	40
DOIs	https://doi.org/10.1039/c3cc47912a
Publication status	Published - 2014 Apr 22

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Pyridine-2-thiolate bridged tin-palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons",

abstract = "Reactions of tin(IV) complexes of the type Sn(PyS)2X2 (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh3)4 provide easy access to novel heterometallic complexes with Pd-Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, 119Sn M{\"o}ssbauer spectroscopy and quantum chemical analyses.",

author = "Erik W{\"a}chtler and Robert Gericke and Lyuben Zhechkov and Thomas Heine and Thorsten Langer and Birgit Gerke and Rainer P{\"o}ttgen and J{\"o}rg Wagler",

year = "2014",

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doi = "10.1039/c3cc47912a",

language = "English",

volume = "50",

pages = "5382--5384",

journal = "Chemical Communications",

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T1 - Pyridine-2-thiolate bridged tin-palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

AU - Wächtler, Erik

AU - Gericke, Robert

AU - Zhechkov, Lyuben

AU - Heine, Thomas

AU - Langer, Thorsten

AU - Gerke, Birgit

AU - Pöttgen, Rainer

AU - Wagler, Jörg

PY - 2014/4/22

Y1 - 2014/4/22

N2 - Reactions of tin(IV) complexes of the type Sn(PyS)2X2 (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh3)4 provide easy access to novel heterometallic complexes with Pd-Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, 119Sn Mössbauer spectroscopy and quantum chemical analyses.

AB - Reactions of tin(IV) complexes of the type Sn(PyS)2X2 (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh3)4 provide easy access to novel heterometallic complexes with Pd-Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, 119Sn Mössbauer spectroscopy and quantum chemical analyses.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Pyridine-2-thiolate bridged tin-palladium complexes with Sn(PdN₂Cl₂), Sn(PdN₂S₂), Sn(PdN₂C₂) and Sn(Pd₂N₄) skeletons

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