Pyridine-2-thiolate bridged tin-palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

Erik Wächtler, Robert Gericke, Lyuben Zhechkov, Thomas Heine, Thorsten Langer, Birgit Gerke, Rainer Pöttgen, Jörg Wagler

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17 Citations (Scopus)

Abstract

Reactions of tin(IV) complexes of the type Sn(PyS)2X2 (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh3)4 provide easy access to novel heterometallic complexes with Pd-Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, 119Sn Mössbauer spectroscopy and quantum chemical analyses.

Original languageEnglish
Pages (from-to)5382-5384
Number of pages3
JournalChemical Communications
Volume50
Issue number40
DOIs
Publication statusPublished - 2014 Apr 22

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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