Pyridine-pyridine π-π stacking interactions in pentacarbonyl[pyridine-4(1H)-thione]tungsten(0)

Moon Gun Choi, Robert J. Angelici

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.

Original languageEnglish
Pages (from-to)808-810
Number of pages3
JournalActa Crystallographica, Section C: Crystal Structure Communications
Volume56
Issue number7
DOIs
Publication statusPublished - 2000 Jul 1

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Carbon Monoxide
Ligands
Thiones
Hydrogen Bonding
Sulfur
Sulfhydryl Compounds
Hydrogen bonds
Atoms
Geometry
pentacarbonyl(pyridine-4(1H)-thione)tungsten(0)
pyridine
compound W

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

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abstract = "In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.",
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Pyridine-pyridine π-π stacking interactions in pentacarbonyl[pyridine-4(1H)-thione]tungsten(0). / Choi, Moon Gun; Angelici, Robert J.

In: Acta Crystallographica, Section C: Crystal Structure Communications, Vol. 56, No. 7, 01.07.2000, p. 808-810.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Choi, Moon Gun

AU - Angelici, Robert J.

PY - 2000/7/1

Y1 - 2000/7/1

N2 - In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.

AB - In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.

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