Pyridine-pyridine π-π stacking interactions in pentacarbonyl[pyridine-4(1H)-thione]tungsten(0)

Moon Gun Choi, Robert J. Angelici

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8 Citations (Scopus)

Abstract

In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.

Original languageEnglish
Pages (from-to)808-810
Number of pages3
JournalActa Crystallographica, Section C: Crystal Structure Communications
Volume56
Issue number7
DOIs
Publication statusPublished - 2000 Jul 1

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All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

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