Pyridine-pyridine π-π stacking interactions in pentacarbonyl[pyridine-4(1H)-thione]tungsten(0)

Moon Gun Choi; Robert J. Angelici

doi:10.1107/S0108270100006168

Pyridine-pyridine π-π stacking interactions in pentacarbonyl[pyridine-4(1H)-thione]tungsten(0)

Moon Gun Choi, Robert J. Angelici

Department of Chemistry

Research output: Contribution to journal › Article

8 Citations (Scopus)

Abstract

In the title compound, [W(C₅H₅NS)(CO)₅], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.

Original language	English
Pages (from-to)	808-810
Number of pages	3
Journal	Acta Crystallographica, Section C: Crystal Structure Communications
Volume	56
Issue number	7
DOIs	https://doi.org/10.1107/S0108270100006168
Publication status	Published - 2000 Jul 1

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All Science Journal Classification (ASJC) codes

Biochemistry, Genetics and Molecular Biology(all)

Cite this

Choi, M. G., & Angelici, R. J. (2000). Pyridine-pyridine π-π stacking interactions in pentacarbonyl[pyridine-4(1H)-thione]tungsten(0). Acta Crystallographica, Section C: Crystal Structure Communications, 56(7), 808-810. https://doi.org/10.1107/S0108270100006168

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AB - In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.

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10.1107/S0108270100006168