Abstract
In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.
| Original language | English |
|---|---|
| Pages (from-to) | 808-810 |
| Number of pages | 3 |
| Journal | Acta Crystallographica, Section C: Crystal Structure Communications |
| Volume | 56 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2000 Jul 1 |
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All Science Journal Classification (ASJC) codes
- Biochemistry, Genetics and Molecular Biology(all)
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Pyridine-pyridine π-π stacking interactions in pentacarbonyl[pyridine-4(1H)-thione]tungsten(0). / Choi, Moon Gun; Angelici, Robert J.
In: Acta Crystallographica, Section C: Crystal Structure Communications, Vol. 56, No. 7, 01.07.2000, p. 808-810.Research output: Contribution to journal › Article
TY - JOUR
T1 - Pyridine-pyridine π-π stacking interactions in pentacarbonyl[pyridine-4(1H)-thione]tungsten(0)
AU - Choi, Moon Gun
AU - Angelici, Robert J.
PY - 2000/7/1
Y1 - 2000/7/1
N2 - In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.
AB - In the title compound, [W(C5H5NS)(CO)5], the pyridine-4-thiol ligand coordinates through the sulfur in the thione mode. The coordination sphere around the W atom is distorted from octahedral geometry by intermolecular hydrogen bonding and steric interactions between the pyridine ring and two CO ligands. An intermolecular pyridine-pyridine ring distance of 3.47 (1) angstrom indicates π-π stacking interactions between these ligand units.
UR - http://www.scopus.com/inward/record.url?scp=0034224638&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0034224638&partnerID=8YFLogxK
U2 - 10.1107/S0108270100006168
DO - 10.1107/S0108270100006168
M3 - Article
C2 - 10935088
AN - SCOPUS:0034224638
VL - 56
SP - 808
EP - 810
JO - Acta Crystallographica, Section C: Crystal Structure Communications
JF - Acta Crystallographica, Section C: Crystal Structure Communications
SN - 0108-2701
IS - 7
ER -