Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence

Dong Su Kim; Jung Woo Park; Chul Ho Jun

doi:10.1039/c2cc36699a

Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)₂ oxidation and Rh(III)-catalyzed N-annulation sequence

Dong Su Kim, Jung Woo Park, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.

Original language	English
Pages (from-to)	11334-11336
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	92
DOIs	https://doi.org/10.1039/c2cc36699a
Publication status	Published - 2012 Oct 24

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc36699a

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abstract = "A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.",

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AB - A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.

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Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)₂ oxidation and Rh(III)-catalyzed N-annulation sequence

Abstract

All Science Journal Classification (ASJC) codes

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