Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence

Dong Su Kim, Jung Woo Park, Chul Ho Jun

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

A new methodology has been developed for the synthesis of pyridines from allyl amines and alkynes, which involves sequential Cu(II)-promoted dehydrogenation of the allylamine and Rh(III)-catalyzed N-annulation of the resulting α,β-unsaturated imine and alkyne.

Original languageEnglish
Pages (from-to)11334-11336
Number of pages3
JournalChemical Communications
Volume48
Issue number92
DOIs
Publication statusPublished - 2012 Oct 24

Fingerprint

Alkynes
Dehydrogenation
Pyridine
Amines
Allylamine
Pyridines
Oxidation
Imines
pyridine

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

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Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence. / Kim, Dong Su; Park, Jung Woo; Jun, Chul Ho.

In: Chemical Communications, Vol. 48, No. 92, 24.10.2012, p. 11334-11336.

Research output: Contribution to journalArticle

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AU - Park, Jung Woo

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