Quantitative analysis of improved bending fracture behavior of large-scale graphene monolayer-intervened flexible oxide thin films

Hong Je Choi, Da Bin Kim, Moo Hyun Kim, Gwan-Hyoung Lee, Yong Soo Cho

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Graphene has been recognized to be potentially useful in creating higher mechanical integrity of electronic components due to its intrinsically superior mechanical properties. Here, we introduce the enhanced bending fracture resistance of flexible inorganic thin films by incorporating a large-scale graphene monolayer, using a typical example of transparent conducting oxide (TCO) materials, i.e., Al-doped ZnO (AZO) thin films. The bending fracture behavior has not been available thus far due to the inefficient coverage of the graphene layer, and also particularly on the basis of the quantitative analysis of fracture parameters. A graphene monolayer of the ∼1 cm × 1 cm scale was successfully transferred onto a flexible polyethylene terephthalate (PET) substrate prior to sputter-deposition of thin films with variable film thicknesses ranging from 50 nm to 200 nm. The highlights of the substantial improvements are the crack-initiating strain of 1.64% and the fracture energy of 364.2 J m-2, which were obtained for the graphene-intervened 200 nm-thick AZO films. These values correspond to respective improvements of ∼61% and ∼272% compared to the reference sample without graphene. Other parameters including the film strength and fracture toughness also support the enhanced bending fracture resistance caused by the graphene-modification.

Original languageEnglish
Pages (from-to)6125-6131
Number of pages7
JournalJournal of Materials Chemistry C
Volume6
Issue number23
DOIs
Publication statusPublished - 2018 Jan 1

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Graphite
Graphene
Oxide films
Monolayers
Thin films
Chemical analysis
Fracture toughness
Sputter deposition
Polyethylene Terephthalates
Fracture energy
Polyethylene terephthalates
Oxides
Film thickness
Cracks
Mechanical properties
Substrates

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Chemistry

Cite this

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title = "Quantitative analysis of improved bending fracture behavior of large-scale graphene monolayer-intervened flexible oxide thin films",
abstract = "Graphene has been recognized to be potentially useful in creating higher mechanical integrity of electronic components due to its intrinsically superior mechanical properties. Here, we introduce the enhanced bending fracture resistance of flexible inorganic thin films by incorporating a large-scale graphene monolayer, using a typical example of transparent conducting oxide (TCO) materials, i.e., Al-doped ZnO (AZO) thin films. The bending fracture behavior has not been available thus far due to the inefficient coverage of the graphene layer, and also particularly on the basis of the quantitative analysis of fracture parameters. A graphene monolayer of the ∼1 cm × 1 cm scale was successfully transferred onto a flexible polyethylene terephthalate (PET) substrate prior to sputter-deposition of thin films with variable film thicknesses ranging from 50 nm to 200 nm. The highlights of the substantial improvements are the crack-initiating strain of 1.64{\%} and the fracture energy of 364.2 J m-2, which were obtained for the graphene-intervened 200 nm-thick AZO films. These values correspond to respective improvements of ∼61{\%} and ∼272{\%} compared to the reference sample without graphene. Other parameters including the film strength and fracture toughness also support the enhanced bending fracture resistance caused by the graphene-modification.",
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Quantitative analysis of improved bending fracture behavior of large-scale graphene monolayer-intervened flexible oxide thin films. / Choi, Hong Je; Kim, Da Bin; Kim, Moo Hyun; Lee, Gwan-Hyoung; Cho, Yong Soo.

In: Journal of Materials Chemistry C, Vol. 6, No. 23, 01.01.2018, p. 6125-6131.

Research output: Contribution to journalArticle

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