Radical deoxygenation of alcohols via their S-methyl dithiocarbonate derivatives with di-n-butylphosphine oxide as hydrogen atom donor

Doo Ok Jang; Dae Hyan Cho; Derek H.R. Barton

doi:10.1055/s-1998-1582

Radical deoxygenation of alcohols via their S-methyl dithiocarbonate derivatives with di-n-butylphosphine oxide as hydrogen atom donor

Doo Ok Jang, Dae Hyan Cho, Derek H.R. Barton

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Various S-methyl dithiocarbonates of tertiary and secondary alcohols are readily deoxygenated in high isolated yields by radical deoxygenation with di-n-butylphosphine oxide and various radical initiators in boiling dioxane. Primary alcohols react similarly in boiling xylenes.

Original language	English
Pages (from-to)	39-40
Number of pages	2
Journal	Synlett
Issue number	1
DOIs	https://doi.org/10.1055/s-1998-1582
Publication status	Published - 1998 Jan

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-1998-1582

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title = "Radical deoxygenation of alcohols via their S-methyl dithiocarbonate derivatives with di-n-butylphosphine oxide as hydrogen atom donor",

abstract = "Various S-methyl dithiocarbonates of tertiary and secondary alcohols are readily deoxygenated in high isolated yields by radical deoxygenation with di-n-butylphosphine oxide and various radical initiators in boiling dioxane. Primary alcohols react similarly in boiling xylenes.",

author = "Jang, {Doo Ok} and Cho, {Dae Hyan} and Barton, {Derek H.R.}",

year = "1998",

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AU - Jang, Doo Ok

AU - Cho, Dae Hyan

AU - Barton, Derek H.R.

PY - 1998/1

Y1 - 1998/1

N2 - Various S-methyl dithiocarbonates of tertiary and secondary alcohols are readily deoxygenated in high isolated yields by radical deoxygenation with di-n-butylphosphine oxide and various radical initiators in boiling dioxane. Primary alcohols react similarly in boiling xylenes.

AB - Various S-methyl dithiocarbonates of tertiary and secondary alcohols are readily deoxygenated in high isolated yields by radical deoxygenation with di-n-butylphosphine oxide and various radical initiators in boiling dioxane. Primary alcohols react similarly in boiling xylenes.

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Radical deoxygenation of alcohols via their S-methyl dithiocarbonate derivatives with di-n-butylphosphine oxide as hydrogen atom donor

Abstract

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