Radical deoxygenation of tertiary alcohols via trifluoroacetates

Joong Gon Kim, Dae Hyan Cho, Doo Ok Jang

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.

Original languageEnglish
Pages (from-to)3031-3033
Number of pages3
JournalTetrahedron Letters
Volume45
Issue number15
DOIs
Publication statusPublished - 2004 Apr 5

Fingerprint

Trifluoroacetic Acid
Stereochemistry
Carbon
Alcohols

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Kim, Joong Gon ; Cho, Dae Hyan ; Jang, Doo Ok. / Radical deoxygenation of tertiary alcohols via trifluoroacetates. In: Tetrahedron Letters. 2004 ; Vol. 45, No. 15. pp. 3031-3033.
@article{81dfab72358d4df9bef8e6c70426f2dd,
title = "Radical deoxygenation of tertiary alcohols via trifluoroacetates",
abstract = "Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.",
author = "Kim, {Joong Gon} and Cho, {Dae Hyan} and Jang, {Doo Ok}",
year = "2004",
month = "4",
day = "5",
doi = "10.1016/j.tetlet.2004.02.109",
language = "English",
volume = "45",
pages = "3031--3033",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "15",

}

Radical deoxygenation of tertiary alcohols via trifluoroacetates. / Kim, Joong Gon; Cho, Dae Hyan; Jang, Doo Ok.

In: Tetrahedron Letters, Vol. 45, No. 15, 05.04.2004, p. 3031-3033.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Radical deoxygenation of tertiary alcohols via trifluoroacetates

AU - Kim, Joong Gon

AU - Cho, Dae Hyan

AU - Jang, Doo Ok

PY - 2004/4/5

Y1 - 2004/4/5

N2 - Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.

AB - Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.

UR - http://www.scopus.com/inward/record.url?scp=1642387676&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1642387676&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2004.02.109

DO - 10.1016/j.tetlet.2004.02.109

M3 - Article

AN - SCOPUS:1642387676

VL - 45

SP - 3031

EP - 3033

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 15

ER -