Radical deoxygenations and dehalogenations with dialkyl phosphites as hydrogen atom sources

Derek H.R. Barton; Doo Ok Jang; Joseph Cs Jaszberenyi

doi:10.1016/S0040-4039(00)74198-0

Radical deoxygenations and dehalogenations with dialkyl phosphites as hydrogen atom sources

Derek H.R. Barton, Doo Ok Jang, Joseph Cs Jaszberenyi

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

Thionocarbonates and xanthates of alcohols, and various halides and phenylselenides can be transformed to the corresponding hydrocarbons with alkyl phosphites and benzoyl peroxide in most cases in high-yielding radical reactions.

Original language	English
Pages (from-to)	2311-2314
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	17
DOIs	https://doi.org/10.1016/S0040-4039(00)74198-0
Publication status	Published - 1992 Apr 17

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)74198-0

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title = "Radical deoxygenations and dehalogenations with dialkyl phosphites as hydrogen atom sources",

abstract = "Thionocarbonates and xanthates of alcohols, and various halides and phenylselenides can be transformed to the corresponding hydrocarbons with alkyl phosphites and benzoyl peroxide in most cases in high-yielding radical reactions.",

author = "Barton, {Derek H.R.} and Jang, {Doo Ok} and Jaszberenyi, {Joseph Cs}",

year = "1992",

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doi = "10.1016/S0040-4039(00)74198-0",

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T1 - Radical deoxygenations and dehalogenations with dialkyl phosphites as hydrogen atom sources

AU - Barton, Derek H.R.

AU - Jang, Doo Ok

AU - Jaszberenyi, Joseph Cs

PY - 1992/4/17

Y1 - 1992/4/17

N2 - Thionocarbonates and xanthates of alcohols, and various halides and phenylselenides can be transformed to the corresponding hydrocarbons with alkyl phosphites and benzoyl peroxide in most cases in high-yielding radical reactions.

AB - Thionocarbonates and xanthates of alcohols, and various halides and phenylselenides can be transformed to the corresponding hydrocarbons with alkyl phosphites and benzoyl peroxide in most cases in high-yielding radical reactions.

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U2 - 10.1016/S0040-4039(00)74198-0

DO - 10.1016/S0040-4039(00)74198-0

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SN - 0040-4039

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SP - 2311

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 17

ER -

Radical deoxygenations and dehalogenations with dialkyl phosphites as hydrogen atom sources

Abstract

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